Ethyl 2-fluoro-3-oxobutanoate

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Names

[ CAS No. ]:
1522-41-4

[ Name ]:
Ethyl 2-fluoro-3-oxobutanoate

[Synonym ]:
Butanoic acid, 2-fluoro-3-oxo-, ethyl ester
Ethyl 2-fluoroacetoacetate
MFCD00215830
2OVYFV1
2-Fluoroacetoacetic Acid Ethyl Ester
2-Fluoro-3-oxo-butanoic acid ethyl ester
Ethyl 2-fluoro-3-oxobutanoate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
170.1±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H9FO3

[ Molecular Weight ]:
148.132

[ Flash Point ]:
55.6±16.7 °C

[ Exact Mass ]:
148.053574

[ PSA ]:
43.37000

[ LogP ]:
0.74

[ Vapour Pressure ]:
1.5±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.390

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
2810.0

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Ethyl acetoacetate
  • ethyl 3-trimethylsilyloxybut-2-enoate
  • Ethyl 2-Chloroacetoacetate
  • acetyl hypofluorite
  • sodium acetyl acetic acid ethyl ester
  • 2-chloro-1,2,2-trifluoroethyl methyl ketone
  • Ethanol
  • TRIFLUOROCHLOROETHYLENE
  • ethyl acetate
  • Ethyl fluoroacetate

DownStream

  • 5-fluoro-2-methoxy-6-methyl-1H-pyrimidin-4-one
  • Ethyl fluoroacetate
  • ethyl 2,2-difluoroacetoacetate
  • Ethyl 2-fluoro-3-oxopentanoate
  • 4(3H)-Pyrimidinone,5-fluoro-2,6-dimethyl-
  • ethyl 2-acetyl-2-fluoro-5-oxohexanoate
  • ethyl 2-acetyl-2-fluoro-5-oxoheptanoate
  • 1-O-ethyl 5-O-methyl 2-acetyl-2-fluoropentanedioate

Articles

Green chemistry: synthesis in micro reactors. Haswell SJ and Watts P.

Green Chem. 5(2) , 240-249, (2003)

Organocatalytic direct aldol reaction between acetone and α-substituted β-keto esters. London G, et al.

J. Mol. Catal. A: Chem. 267(1) , 98-101, (2007)

Fluorinated [1,2,4] triazolo [1,5-a] pyrimidines and [1,2,4] triazolo [5,1-c][1,2,4] triazines*. Ulomskiy EN, et al.

Chem. Heterocycl. Comp. 47(9) , 1164-1169, (2011)


More Articles

Related Compounds

  • ethyl 2-fluoro-3-nitrobenzoate
  • ethyl 2-fluoro-3-hydroxybutanoate
  • ethyl 2-fluoro-3-phenylpropanoate
  • Ethyl 2-fluoro-3-(trifluoromethyl)benzoate
  • ethyl 2-fluoro-3-oxohexanoate
  • ethyl 2-fluoro-3-methyl-5-phenylpent-2-enoate
  • 3-(Pyrrolidin-1-yl)-5-(trifluoromethoxy)benzoic Acid
  • 1-(3-Fluoropyridin-2-yl)-3-hydroxycyclobutane-1-carbonitrile
  • 5-Amino-1,2,3,4-tetrahydro-1,4-methanonaphthalen-9-ol
  • 2-Bromo-3-(methylthio)phenol
  • 2-Cyclobutyl-3-fluoropyridine
  • Benzamide, 3,5-dichloro-N-(3,3-dimethyl-2-oxobutyl)-
  • 1-{[4-(Trifluoromethyl)piperidin-1-yl]methyl}cyclopentan-1-ol
  • Rel-((1r,3r)-3-fluoro-1-(3-fluoropyridin-2-yl)cyclobutyl)methanamine
  • 2-(2,3-Dihydrobenzofuran-5-yl)morpholine
  • N-(6-bromopyridin-2-yl)formamide
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