Carbon monooxide-ruthenium (4:1)

Names

[ Name ]:
Carbon monooxide-ruthenium (4:1)

[Synonym ]:
EINECS 239-287-4
Carbon monooxide - ruthenium (4:1)
Triruthenium dodecacarbonyl
MFCD00011209
Triruthenium dodecacarbonyl,Ruthenium carbonyl,tri-Ruthenium dodecacarbonyl

Chemical & Physical Properties

[ Melting Point ]:
150 °C

[ Molecular Formula ]:
C₁₂O₁₂Ru₃

[ Molecular Weight ]:
639.331

[ Exact Mass ]:
641.652161

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H332

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F: Flammable;Xn: Harmful;

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
1325

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

carbon monoxide
ruthenium chloride
ruthenium pentacarbonyl
H3Ru3(μ3-methoxymethylidyne)(carbonyl)9
HRu3(μ2-N(Ph)COMe)(CO)10
Trifluoromethanesulfonic acid

DownStream

Ruthenium
carbon monoxide
Ru4(CO)12(μ3-Se)4
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
(4,4-dimethyl-1-phenylpenta-1,2-dienyl)benzene

Articles

Ru-catalyzed intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide leading to alpha-pyrones.

Org. Lett. 9 , 587, (2007)

Ruthenium catalyzes a carbonylative [3+2+1] cycloaddition, using silylacetylenes, alpha,beta-unsaturated ketones, and CO as the starting materials, providing the new method for the synthesis of tetras...

Tetrahedron Lett. 22 , 1541, (1981)

J. Am. Chem. Soc. 106 , 4647, (1984)

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