3-Methoxybenzonitrile

Suppliers

Names

[ Name ]:
3-Methoxybenzonitrile

[Synonym ]:
Benzonitrile,3-methoxy
3-methoxybenzylnitrile
3-Methoxybenzonitrile
m-Anisonitrile (8CI)
3-Cyanoanisole
MFCD00001801
m-cyanoanisole
EINECS 216-201-3
m-MeOC6H4CN
m-Methoxybenzonitrile
1-cyano-3-methoxybenzene
3-Methoxybenzolcarbonitril
m-Methoxybenzontrile
3-anisonitrile
Benzonitrile, 3-methoxy-
m-Anisonitrile
3-methoxy-benzonitrile
Benzonitrile, m-methoxy-

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
233.2±0.0 °C at 760 mmHg

[ Melting Point ]:
20-22°C

[ Molecular Formula ]:
C₈H₇NO

[ Molecular Weight ]:
133.147

[ Flash Point ]:
105.0±0.0 °C

[ Exact Mass ]:
133.052765

[ PSA ]:
33.02000

[ LogP ]:
1.45

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.527

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332-H315-H319-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S26-S37/39-S36/37

[ RIDADR ]:
3276

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2926909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

m-Anisaldehyde
m-Anisylamine
Trimethyl borate
potassium 4-cyanobenzoate
m-Bromoanisole
3-methoxybenzaldoxime
3-Methoxybenzyl alcohol
1,10-Phenanthroline
3-Iodobenzonitrile
Acetone cyanohydrin

DownStream

3-Methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile
m-Anisylamine
cyclopentyl-(3-methoxyphenyl)methanone
3'-Methoxypropiophenone
2-Methoxy-4-pyridinecarbothioamide
DMeOB
4-Methoxybenzophenone
3-Methoxybenzoic acid
m-Anisaldehyde
3-Cyanophenol

Customs

[ HS Code ]: 2926909090

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Vibrational analysis of substituted benzonitriles. III. Transferability of force constants--the case of some halogeno-, methoxy- and nitro-benzonitriles.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 53A(12) , 2041-8, (1997)

A zero-order normal coordinate analysis of both the in-plane and out-of-plane vibrations was made for 2-chloro, 6-fluorobenzonitrile, s-trichlorobenzonitrile, p- and m-methoxybenzonitriles and m-nitro...

Theoretical surface-enhanced Raman spectra study of substituted benzenes II. Density functional theoretical SERS modelling of o-, m-, and p-methoxybenzonitrile.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 71(3) , 1074-9, (2008)

The SERS modelling of o-, m-, and p-methoxybenzonitrile has been performed following the same methodology that in Part I. Optimized structure obtained from DFT calculations in a B3LYP-LANL2DZ level of...

[Catalysts for demethylation of methoxybenzonitrile in liquid-phase (author's transl)].

Yakugaku Zasshi 100(6) , 668-71, (1980)