2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl

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Names

[ CAS No. ]:
153305-67-0

[ Name ]:
2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl

[Synonym ]:
p-tol-BINAP
TifluadoM/KC-5103
rac-Tol-BINAP
rac-2,2‘-Bis(di-p-tolylphosphino)-1,1‘-binaphthyl
rac-tolyl-BINAP

Chemical & Physical Properties

[ Melting Point ]:
252-256ºC

[ Molecular Formula ]:
C48H40P2

[ Molecular Weight ]:
678.77900

[ Exact Mass ]:
678.26100

[ PSA ]:
27.18000

[ LogP ]:
10.41000

[ Appearance of Characters ]:
Crystalline Powder | White to off-white

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

Synthetic Route

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Precursor & DownStream

Precursor

  • (+/-)-2,2-Dibromo-1,1-Binaphthyl
  • (R)-trifluoro-methanesulfonic acid 2’-trifluoromethanesulfonyloxy [1,1’]binapthalenyl-2-yl ester

DownStream

Related Compounds

  • (2R,5R)-1-{[(9H-fluoren-9-yl)methoxy]carbonyl}-5-(4-methoxyphenyl)pyrrolidine-2-carboxylic acid
  • 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}[5-(4-fluorophenyl)thieno[2,3-d]pyrimidin-4-yl]amino)acetic acid
  • 4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-(2-hydroxyethoxy)benzoic acid
  • 4-({[(9H-fluoren-9-yl)methoxy]carbonyl}[(1-methyl-1H-pyrazol-4-yl)methyl]amino)benzoic acid
  • rac-(2R,4S)-4-ethyl-1-{[(9H-fluoren-9-yl)methoxy]carbonyl}piperidine-2-carboxylic acid
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}[(1,3-thiazol-5-yl)methyl]amino)benzoic acid
  • 2-({[(9H-fluoren-9-yl)methoxy]carbonyl}(4-methyl-1,3-thiazol-2-yl)amino)butanoic acid
  • Tert-butyl 3-[(fluorosulfonyl)methyl]-3-(trifluoromethyl)pyrrolidine-1-carboxylate
  • tert-butyl N-[2-(chlorosulfonyl)-1-(oxan-3-yl)ethyl]carbamate
  • tert-butyl N-{1-[(chlorosulfonyl)methyl]cyclobutyl}-N-cyclopropylcarbamate
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