[(Difluoromethyl)sulfonyl]benzene

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Names

[ CAS No. ]:
1535-65-5

[ Name ]:
[(Difluoromethyl)sulfonyl]benzene

[Synonym ]:
[(Difluoromethyl)sulfonyl]benzene
Benzene, [(difluoromethyl)sulfonyl]-
(Difluoromethyl)sulfonylbenzene
Difluoromethyl Phenyl Sulfone
PhSO2CF2H [(Difluoromethyl)sulfonyl]benzene

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
289.5±40.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H6F2O2S

[ Molecular Weight ]:
192.183

[ Flash Point ]:
128.9±27.3 °C

[ Exact Mass ]:
192.005661

[ PSA ]:
42.52000

[ LogP ]:
1.46

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.479

[ Storage condition ]:
-20℃

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2904909090

Precursor & DownStream

Precursor

  • [(Difluoromethyl)thio]benzene
  • 4-Chlorostyrene
  • (3E)-1,1-difluoro-2,4-diphenyl-1-(phenylsulfonyl)but-3-en-2-ol
  • [difluoro(phenylsulfonyl)Methyl]triMethyl-Silane
  • (Bromodifluoromethyl)trimethylsilane
  • Sodium benzenesulfinate
  • [[difluoro(trimethylsilyl)methyl]thio]-Benzene
  • Thiophenol
  • 2-(Fluorosulfonyl)difluoroacetic acid

DownStream

  • (Difluoromethoxy)benzene
  • 1,1-DIFLUORODIMETHYL ETHER
  • [(Difluoromethyl)thio]benzene
  • Phenylsulfinic acid
  • 1-(difluoromethylsulfonyl)-3-nitrobenzene
  • Furfuryl alcohol
  • α-(difluoro[phenylsulfonyl]methyl)-2-furanmethanol
  • (Difluoromethyl)(trimethyl)silane
  • [benzenesulfonyl(difluoro)methyl]sulfanylbenzene

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones: probing the hard/soft nature of fluorinated carbanions.

J. Org. Chem. 15th ed., 73 , 5699-5713, (2008)

We have successfully accomplished the nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones. It was found that for acylic alpha,beta-enones, altho...

Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.

J. Org. Chem. 11th ed., 68 , 4457-4463, (2003)

A new and efficient method for the preparation of tri- and difluoromethylsilanes using magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes is reported using tri- and diflu...

Facile synthesis of chiral alpha-difluoromethyl amines from N-(tert-butylsulfinyl)aldimines.

Angew. Chem. Int. Ed. Engl. 36th ed., 44 , 5882-5886, (2005)


More Articles

Related Compounds

  • 1-bromo-4-[(difluoromethyl)sulfonyl]benzene
  • 1-(BROMOMETHYL)-4-[(DIFLUOROMETHYL)SULFONYL]BENZENE
  • 4-[(difluoromethyl)sulfonyl]benzenesulfonyl chloride
  • (DIFLUOROMETHYL)BENZENE
  • [(Dichloromethyl)sulfonyl]benzene
  • ((cyclohexylmethyl)sulfonyl)benzene