Di-(2-picolyl)amine

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Names

[ CAS No. ]:
1539-42-0

[ Name ]:
Di-(2-picolyl)amine

[Synonym ]:
Di-2-picolylamine
bis(2-pyridylmethyl)amine
Iminobis(methylene-2-pyridine)
bis(pyridylmethyl)amine
2-Pyridinemethanamine, N- (2-pyridinylmethyl)-
bis-(2-picolyl)amine
α,α'-Iminodi(2-picoline)
2,2'-Dipicolylamine
MFCD00129044
1-(Pyridin-2-yl)-N-(pyridin-2-ylmethyl)methanamine
di-(2-picolyl)-amine
di(2-picolyl)amine
EINECS 216-266-8
1-(2-Pyridinyl)-N-(2-pyridinylmethyl)methanamine
Dipicolylamine
2-Pyridinemethanamine, N-(2-pyridinylmethyl)-
N,N-bis(2-picolyl)amine

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
322.2±27.0 °C at 760 mmHg

[ Molecular Formula ]:
C12H13N3

[ Molecular Weight ]:
199.252

[ Flash Point ]:
148.6±23.7 °C

[ Exact Mass ]:
199.110947

[ PSA ]:
37.81000

[ LogP ]:
0.44

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.589

[ Water Solubility ]:
water: soluble (partially miscible)(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-Picolylamine
  • 2-(bromomethyl)pyridine hydrobromide
  • 2-Pyridinecarboxaldehyde
  • 3-phenylpropanamine
  • 2-cyanopyridine
  • 2-nitro-N,N-bis(pyridin-2-ylmethyl)benzenesulfonamide
  • (di-2-pyridylmethyl-amide)2Fe
  • 2-(Methylamino)pyridine

DownStream

  • 2-[[bis(pyridin-2-ylmethyl)amino]methyl]benzenethiol
  • Methyl 6-(bromomethyl)nicotinate
  • 1 3-BIS[BIS(2-PYRIDYLMETHYL)AMINO]-2-PRO
  • 2-[bis(pyridin-2-ylmethyl)amino]acetic acid
  • 2,6-Bis{[bis(2-pyridylMethyl)aMino]Methyl}-4-Methylphenol
  • 2-pyridin-2-yl-N,N-bis(pyridin-2-ylmethyl)ethanamine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Identifying chelators for metalloprotein inhibitors using a fragment-based approach.

J. Med. Chem. 54 , 591-602, (2011)

Fragment-based lead design (FBLD) has been used to identify new metal-binding groups for metalloenzyme inhibitors. When screened at 1 mM, a chelator fragment library (CFL-1.1) of 96 compounds produced...

Efficient hydrolytic cleavage of plasmid DNA by chloro-cobalt(II) complexes based on sterically hindered pyridyl tripod tetraamine ligands: synthesis, crystal structure and DNA cleavage.

Dalton Trans. 43(26) , 10086-103, (2014)

Four new cobalt(ii) complexes [Co(6-MeTPA)Cl]ClO4/PF6 (2/2a), [Co(6-Me2TPA)Cl]ClO4/PF6 (3/3a), [Co(BPQA)Cl]ClO4/PF6 (4/4a) and [Co(BQPA)Cl]ClO4/PF6 (5/5a) as well as [Co(TPA)Cl]ClO4 (1) where TPA = tr...

Formation of a metal-to-nitrogen bond of normal length by a neutral sufonamide group within a tridentate ligand. A new approach to radiopharmaceutical bioconjugation.

Inorg. Chem. 52(5) , 2412-21, (2013)

We demonstrate that a tertiary sulfonamide group, N(SO2R)R'2, can rehybridize to form a M-N bond of normal length even when the group is in a linear tridentate ligand, such as in the new tridentate N(...


More Articles

Related Compounds

  • Di-(2-picolyl)aminomethyl BODIPY
  • N,N-di(2-picolyl)-4-methylbenzenesulfonamide
  • N-ethyl-N,N-bis(2-pyridylmethyl)amine
  • N'-Nitrosopentyl-(2-picolyl)amine
  • 1-O-octadecyl-2,3-O-di-(2-picolyl)-glycerol
  • 6,6'-Dimethyl-2,2'-bipyridine
  • 3-chloro-4-fluoro-5-(1-methyl-1H-pyrazol-4-yl)aniline
  • 5-(butan-2-yl)-4-cyclopentyl-4H-1,2,4-triazole-3-thiol
  • 3-(5-Methyl-1,2-oxazol-3-yl)prop-2-ynoic acid
  • tert-butyl N-(cyclopropylmethyl)-N-(2-oxobut-3-en-1-yl)carbamate
  • Tert-butyl 4-methyl-3-(prop-2-enoyl)piperidine-1-carboxylate
  • tert-butyl N-methyl-N-[2-(1-methyl-1H-1,2,3,4-tetrazol-5-yl)-2-oxoethyl]carbamate
  • 2-(4-{[(Benzyloxy)carbonyl]amino}-1-[(tert-butoxy)carbonyl]-2,2-dimethylpiperidin-4-yl)acetic acid
  • 8-Bromo-5-fluoro-1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid
  • 3-{[(Tert-butoxy)carbonyl]amino}-3-(dimethyl-1,3-thiazol-5-yl)propanoic acid
  • 3-{[(Tert-butoxy)carbonyl]amino}-3-cyclopropyl-4-methylpentanoic acid