Dichlororuthenium-triphenylphosphine (1:3)

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Names

[ CAS No. ]:
15529-49-4

[ Name ]:
Dichlororuthenium-triphenylphosphine (1:3)

[Synonym ]:
Dichlorotris(triphenylphosphine)ruthenium(II)
Ruthenium(2+) chloride triphenylphosphine (1:2:3)
Tris(triphenylphosphine)ruthenium(II) dichloride
Dichlororuthenium - triphenylphosphine (1:3)
Phosphine, triphenyl-, ruthenium(2+) salt, hydrochloride (3:1:2)
EINECS 239-569-7
Dichlorotris(triphenylphosphino)ruthenium (II)
MFCD00013077
Tris(triphenylphosphine)ruthenium(II) chloride
Tris(triphenylphosphine)ruthenium(II)chloride

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760 mmHg

[ Melting Point ]:
159 °C

[ Molecular Formula ]:
C54H45Cl2P3Ru

[ Molecular Weight ]:
958.832

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
958.115479

[ PSA ]:
40.77000

[ LogP ]:
11.71340

[ Vapour Pressure ]:
4.74E-05mmHg at 25°C

[ Storage condition ]:
Refrigerator

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21

[ Safety Phrases ]:
S36/37-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

Transition-metal-catalyzed rearrangement of allenyl sulfides: a route to furan derivatives.

Angew. Chem. Int. Ed. Engl. 46 , 1905, (2007)

Cross-coupling reaction between alcohols through sp3 C-H activation catalyzed by a ruthenium/Lewis acid system.

Chemistry 33th ed., 14 , 10201-10205, (2008)


More Articles

Related Compounds

  • Bromocopper-triphenylphosphine (1:3)
  • dichlororuthenium,1,4,8,11-tetrazacyclotetradecane
  • Dichloro(p-cymene)tricyclohexylphosphineruthenium(II)
  • Dichlororuthenium-hexamethylbenzene (1:1)
  • dichlororuthenium; methylsulfinylmethane
  • dichlororuthenium, 2-pyrazin-2-ylpyrazine
  • Butanoic acid, 3-oxo-4-(phenylsulfonyl)-, ethyl ester
  • (1R,2R)-2-[benzyl(methyl)amino]cyclohexan-1-ol
  • (S)-7,8-Difluoro-3-methyl-4-(tosyl-L-prolyl)-3,4-dihydro-2H-benzo[B][1,4]oxazine
  • 2-{[(Benzyloxy)carbonyl]amino}-4,4-dimethylpentanoic acid
  • trans-2-(3,4-Dimethoxyphenyl)cyclopentanol
  • Benzamide,4-[[5-(aminosulfonyl)-2-thienyl]thio]-
  • (2S)-2-{[(benzyloxy)carbonyl]amino}-3-sulfanylpropanoic acid
  • 2-(Azidomethyl)-4-nitrophenol
  • 5-(3-Aminophenylamino)pentan-1-ol
  • Ethyl 2-[[(4-methoxyphenyl)amino]thioxomethyl]butanoate
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