Dichlororuthenium-triphenylphosphine (1:3)

Suppliers

Names

[ Name ]:
Dichlororuthenium-triphenylphosphine (1:3)

[Synonym ]:
Dichlorotris(triphenylphosphine)ruthenium(II)
Ruthenium(2+) chloride triphenylphosphine (1:2:3)
Tris(triphenylphosphine)ruthenium(II) dichloride
Dichlororuthenium - triphenylphosphine (1:3)
Phosphine, triphenyl-, ruthenium(2+) salt, hydrochloride (3:1:2)
EINECS 239-569-7
Dichlorotris(triphenylphosphino)ruthenium (II)
MFCD00013077
Tris(triphenylphosphine)ruthenium(II) chloride
Tris(triphenylphosphine)ruthenium(II)chloride

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760 mmHg

[ Melting Point ]:
159 °C

[ Molecular Formula ]:
C₅₄H₄₅Cl₂P₃Ru

[ Molecular Weight ]:
958.832

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
958.115479

[ PSA ]:
40.77000

[ LogP ]:
11.71340

[ Vapour Pressure ]:
4.74E-05mmHg at 25°C

[ Storage condition ]:
Refrigerator

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302 + H312 + H332

[ Precautionary Statements ]:
P280

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21

[ Safety Phrases ]:
S36/37-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

Transition-metal-catalyzed rearrangement of allenyl sulfides: a route to furan derivatives.

Angew. Chem. Int. Ed. Engl. 46 , 1905, (2007)

Cross-coupling reaction between alcohols through sp3 C-H activation catalyzed by a ruthenium/Lewis acid system.

Chemistry 33th ed., 14 , 10201-10205, (2008)

Bromocopper-triphenylphosphine (1:3)
dichlororuthenium,1,4,8,11-tetrazacyclotetradecane
Dichloro(p-cymene)tricyclohexylphosphineruthenium(II)
Dichlororuthenium-hexamethylbenzene (1:1)
dichlororuthenium; methylsulfinylmethane
dichlororuthenium, 2-pyrazin-2-ylpyrazine
Methyl 2-((4-methoxybenzyl)amino)benzoate
4-(3-(Trifluoromethyl)phenyl)pyridin-2-amine
2,4-Dichloro-6-(2-fluorophenyl)-1,3,5-triazine
2,4-Dichloro-6-[2-(trifluoromethyl)phenyl]-1,3,5-triazine
2,4-Dichloro-6-[3-(trifluoromethyl)phenyl]-1,3,5-triazine
2-ethoxy-N-(3-hydroxypropyl)-4,5-dimethylbenzenesulfonamide
2-ethoxy-N-(3-hydroxypropyl)-5-isopropyl-4-methylbenzenesulfonamide
2-methoxy-5-methyl-N-(6-methyl-2-pyridinyl)benzenesulfonamide
(1R,2R)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate
(1S,2S)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate