(Z,Z)-2,4-HEXADIENEDINITRILE

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Names

[ CAS No. ]:
1557-59-1

[ Name ]:
(Z,Z)-2,4-HEXADIENEDINITRILE

[Synonym ]:
hexa-2c,4c-dienedinitrile
MFCD00075424

Chemical & Physical Properties

[ Density]:
1.024g/cm3

[ Boiling Point ]:
244.7ºC at 760 mmHg

[ Melting Point ]:
128-131ºC(lit.)

[ Molecular Formula ]:
C6H4N2

[ Molecular Weight ]:
104.10900

[ Flash Point ]:
115.6ºC

[ Exact Mass ]:
104.03700

[ PSA ]:
47.58000

[ LogP ]:
1.14596

[ Vapour Pressure ]:
0.03mmHg at 25°C

[ Index of Refraction ]:
1.498

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H312-H315-H319-H332-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
20/21/22-36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • o-Phenylenediamine
  • benzene
  • 1,2-diazidobenzene
  • Dimethyl but-2-ynedioate
  • 1,2,3-triazolo[1,2-a]benzotriazole
  • 1,3-Diazidobenzene
  • cyclohexane
  • Sodium cyanide
  • 1,4-Dichlorbut-2-in

DownStream

  • 1,6-Hexanediamine

Articles

Copper-catalyzed oxidation of o-phenylenediamines to cis, cis-mucononitriles. Kajimoto T, et al.

J. Org. Chem. 41(8) , 1389-93, (1976)

13C MAS NMR Spectra of cis, cis-Mucononitrile in Liquid-Crystalline Media and in the Solid State. Orientation of the Carbon Chemical-Shift Tensors. Ramanathan KV, et al.

J. Magn. Reson. 123(2) , 196-200, (1996)

Regiochemistry of platinum-catalyzed hydrophosphination of a diene. Formation of the chiral diphosphine Et2PCH (CN) CH (CH2CH2CN) PEt2 via monophosphine intermediates. Kovacik I, et al.

Organometallics 25(2) , 536-39, (2006)


More Articles

Related Compounds

  • (Z,Z)-2,4-Dihydroxy-4-(1-indanon-2-yliden)-2-butensaeuremethylester
  • (Z,Z)-2,4-Dihydroxy-4-(1-indanon-2-yliden)-2-butensaeure
  • (2Z,4Z)-hexadienoic acid methyl ester
  • methyl (2Z,4Z)-2,4-decadienoate
  • (2Z,4Z)-hexa-2,4-dienedial
  • 2,4-Hexadienedioicacid, 1,6-dimethyl ester
  • 2-{4-[(2S)-3-(dimethylamino)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoyl]morpholin-2-yl}acetic acid
  • 2-(But-3-yn-2-yl)-6-chloropyridine
  • 6-[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)pentanamido]-4,4-dimethylhexanoic acid
  • 3-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2,2,4-trimethylpentanamido]-2-methoxypropanoic acid
  • 3-(1H-1,3-benzodiazol-5-yl)-2-hydroxy-2-methylpropanoic acid
  • methyl 3-(5-methyl-1H-pyrazol-1-yl)-2-(methylamino)butanoate
  • (2S)-4-[3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2,2,4-trimethylpentanamido]-2-hydroxybutanoic acid
  • 5-(4-Methylpent-1-en-1-yl)-1,3-oxazole
  • 6-Nitroso-6-azaspiro[2.5]octane
  • tert-butyl N-(2-cyanocyclopentyl)-N-methylcarbamate
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