SnAP 3Me-M Reagent

Names

[ CAS No. ]:
1557288-09-1

[ Name ]:
SnAP 3Me-M Reagent

Chemical & Physical Properties

[ Density]:
1.102 at 25℃

[ Molecular Formula ]:
C16H37NOSn

[ Molecular Weight ]:
378.18

[ Appearance of Characters ]:
liquid

[ Index of Refraction ]:
n/D1.479

[ Storage condition ]:
-20°C

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H315-H319-H335-H410

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310-P305 + P351 + P338-P311

[ RIDADR ]:
UN 2788 6.1 / PGIII

Articles

SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.

Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)

SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.

Nature Chemistry 6(4) , 310-4, (2014)

Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially ...

One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.

J. Am. Chem. Soc. 136(51) , 17726-9, (2014)

The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected ...


More Articles

Related Compounds

  • SnAP M Reagent
  • SnAP 2Me-M Reagent
  • SnAP Pip Reagent
  • SnAP DA Reagent
  • 3-[(Tributylstannyl)methoxy]-1-propanamine
  • SnAP-TM Reagent
  • 3-Aminomethyl-2-fluoro-4-iodopyridine
  • 2-(4-Amino-1,2-dimethylpiperidin-4-yl)acetamide
  • 3-(3-Fluoropyridin-2-yl)butanoic acid
  • 3-[2-Fluoro-5-(trifluoromethyl)phenyl]piperidine
  • 1-[1-(5-Chlorofuran-2-yl)cyclopropyl]ethan-1-amine
  • 1-(1-Benzofuran-5-yl)cyclopropane-1-carbaldehyde
  • (1-Cyclopropylpiperidin-2-yl)methanamine
  • 7-Bromo-4-fluorobenzofuran-2-carboxylic acid
  • 3-hydroxy-3-(1H-pyrrol-3-yl)propanoic acid
  • 3-fluoro-5-methoxy-N-methylaniline
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