Diethyl 1,1-cyclopropanedicarboxylate

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Names

[ CAS No. ]:
1559-02-0

[ Name ]:
Diethyl 1,1-cyclopropanedicarboxylate

[Synonym ]:
cyclopropane-1,1-dicarboxylic acid diethyl ester
MFCD00013727
Diethyl-1,1-cyclopropanedicarboxylate
diethyl cyclopropane-1,1-dicarboxylic acid
diethyl cyclopropane-1,1'-dicarboxylate
1,1-diethyl cyclopropane-1,1-dicarboxylate
1,1-Cyclopropanedicarboxylic acid, diethyl ester
Diethyl 1,1-cyclopropanedicarboxylate
Diethylcyclopropan-1,1-dicarboxylat
diethyl cyclopropane-1,1-dicarboxylate
1,1-Cyclopropanedicarboxylic acid diethyl ester
EINECS 209-917-2

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
219.2±0.0 °C at 760 mmHg

[ Melting Point ]:
134-136 °C(lit.)

[ Molecular Formula ]:
C9H14O4

[ Molecular Weight ]:
186.205

[ Flash Point ]:
86.7±0.0 °C

[ Exact Mass ]:
186.089203

[ PSA ]:
52.60000

[ LogP ]:
1.18

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.474

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S24/25-S23

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ HS Code ]:
2917209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,2-Dibromoethane
  • Diethyl malonate
  • dichloroethane
  • Potassium carbonate
  • S-Ethenyl-S-(4-methylphenyl)-N-tolylsulfilimine
  • S-ethenyl-S-phenyl-N-(toluene-4-sulfonyl)sulfilimine
  • Diethyl methylenemalonate
  • 2-(4-chloro-phenyl)-3-oxo-3-phenyl-propionic acid amide
  • diethyl 2-(2-chloroethyl)propanedioate

DownStream

  • 1-N,1-N'-dibromocyclopropane-1,1-dicarboxamide
  • diethyl 2-(2-acetyloxyethyl)propanedioate
  • 1,1-Bis(Hydroxymethyl)cyclopropane
  • Ethyl 2-oxo-3-pyrrolidinecarboxylate
  • diethyl 2-(2-chloroethyl)propanedioate
  • DIETHYL 4-PENTENYLMALONATE
  • 1,1,3-Propanetricarboxylicacid, 1,1,3-triethyl ester
  • 5,7-Dioxa-6-thia-spiro[2,5]octane-6-oxide
  • diethyl (3-oxopropyl)malonate
  • 1-(4-Fluorophenylcarbamoyl)cyclopropanecarboxylic acid

Customs

[ HS Code ]: 2917209090

[ Summary ]:
2917209090 other cyclanic, cyclenic or cyclotherpenic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Nucleophilic ring-opening additions to 1, 1-disubstituted cyclopropanes. Stewart JM and Westberg HH.

J. Org. Chem. 30(6) , 1951-55, (1965)


More Articles

Related Compounds

  • diethyl [1,1-dimethyl-2-(4-methyl-2,5-dioxoimidazolidin-4-yl)ethyl]phosphonate
  • diethyl <1,1-difluoro-3(S),4-dihydroxybutyl>phosphonate
  • diethyl 1-(1-ethoxyethyl)ethylphosphonate
  • diethyl 1,1-dichloro-2-oxo-n-butylphosphonate
  • diethyl 1,1-difluoro-3-propynephosphonate
  • diethyl 1,1-difluoro-3-iodo-5-carbethoxyhexylphosphonate
  • 4-Amino-4-[5-fluoro-2-(trifluoromethyl)phenyl]cyclohexan-1-ol
  • 1-(3-hydroxybutyl)-5-(3-methylbutyl)-1H-1,2,3-triazole-4-carboxamide
  • 1,1,1-Trifluoro-3-[4-methyl-3-(trifluoromethyl)phenyl]propan-2-ol
  • 1-(1-ethyl-1H-pyrazol-3-yl)-3-oxocyclobutane-1-carboxylic acid
  • 3-(3-Bromo-2,4-dimethylphenyl)propane-1-thiol
  • 1-[2-Fluoro-5-(trifluoromethyl)phenyl]-3-oxocyclobutane-1-carboxylic acid
  • 3-(3-Chloro-2,4-difluorophenyl)-3-hydroxypropanenitrile
  • Tert-butyl 2-(2-amino-3,3-difluoro-2-methylpropyl)morpholine-4-carboxylate
  • 4-Fluoro-1-(2-nitroethyl)-2-(trifluoromethyl)benzene
  • methyl 3,4-dioxo-2H,3H,4H,6H,7H,8H-pyrrolo[2,1-c][1,2,4]triazine-7-carboxylate
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