1,3-DIBROMOTETRAFLUOROBENZENE

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Names

[ CAS No. ]:
1559-87-1

[ Name ]:
1,3-DIBROMOTETRAFLUOROBENZENE

[Synonym ]:
1,3-dibromo-tetrafluorobenzene
EINECS 216-326-3
1,3-Dibrom-2,4,5,6-tetrafluorbenzol
1,3-DibroMotetrafluorobenzene
1,3-Dibromo-2,4,5,6-tetrafluorobenzene
1,3-Dibrom-tetrafluor-benzol
2,4,5,6-Tetrafluor-1,3-dibrombenzol
MFCD00031533
meta-Dibromtetrafluorbenzol

Chemical & Physical Properties

[ Density]:
2.18 g/mL at 25 °C(lit.)

[ Boiling Point ]:
200 °C(lit.)

[ Molecular Formula ]:
C6Br2F4

[ Molecular Weight ]:
307.86600

[ Flash Point ]:
198 °F

[ Exact Mass ]:
305.83000

[ LogP ]:
3.76800

[ Vapour Pressure ]:
0.992mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.516(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ WGK Germany ]:
3

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromo-2,3,4,6-tetrafluorobenzene

DownStream

  • 1,2,3,5-Tetrafluorobenzene
  • 1-Bromo-2,3,4,6-tetrafluorobenzene
  • 1,2,3,4,5-pentafluoro-6-[2,3,4,6-tetrafluoro-5-(2,3,4,5,6-pentafluorophenyl)phenyl]benzene

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Strategies for the synthesis of fluorinated liquid crystal derivatives from perbromofluoroaromatic systems. Kenwright AM, et al.

Tetrahedron 66(52) , 9819-9827, (2010)

C–BrO supramolecular synthon: in situ cryocrystallography of low melting halogen-bonded complexes.

CrystEngComm 14(13) , 4259-4261, (2012)

N.Br halogen bonding: one-dimensional infinite chains through the self-assembly of dibromotetrafluorobenzenes with dipyridyl derivatives.

Chemistry 9(16) , 3974-83, (2003)

The N.Br halogen bonding drives the self-assembly of 1,4-dibromotetrafluorobenzene (1 a) and its 1,3 or 1,2 analogues (1 b,c, respectively) with dipyridyl derivatives 2 a,b. The isomeric supramolecula...


More Articles

Related Compounds

  • 1,3-dimethyl-2H-pyrazolo[3,4-d]pyrimidine-4,6-dione
  • 1,3-dipropyl-8-(2-aminoethylaminothiocarbonyl-(4-aminophenyl)(aminothiocarbonyl-(2-aminoethylaminocarbonyl-(4-methoxy(phenyl)))))xanthine
  • 1,3,5-Triazine-2,4(1H,3H)-dione, 1-acetyldihydro- (9CI)
  • 1,3-Dioxolan-4-one,5-methyl-2-propyl-
  • 1,3-Methano-1H-cyclopenta[b]quinoxaline,2,3-dihydro-(9CI)
  • 1-(3-phenylbut-3-enyl)piperidine
  • 2-Methyl-4-({1-[(2-methyl-1,3-oxazol-4-yl)methyl]piperidin-3-yl}methoxy)pyridine
  • 2-{3-[(Pyridin-3-yloxy)methyl]azetidin-1-yl}-4-(trifluoromethyl)pyrimidine
  • 2-({1-[(4-methyl-4H-1,2,4-triazol-3-yl)methyl]piperidin-3-yl}methoxy)-3-(trifluoromethyl)pyridine
  • 2-{[1-(3-Methyl-1,2,4-thiadiazol-5-yl)piperidin-3-yl]methoxy}pyrimidine
  • 5-(4-{[(6-Cyclobutylpyrimidin-4-yl)oxy]methyl}piperidine-1-carbonyl)pyrrolidin-2-one
  • 1-Cyclohexyl-2-({pyrido[2,3-d]pyrimidin-4-yl}amino)ethan-1-ol
  • 4-{[(5-Bromopyrimidin-2-yl)amino]methyl}-4,5,6,7-tetrahydro-1-benzofuran-4-ol
  • 5-Methyl-2-{[1-(pyrazin-2-yl)piperidin-3-yl]methoxy}pyrimidine
  • 2-(3-{[(5-Methylpyrimidin-2-yl)oxy]methyl}piperidin-1-yl)pyrimidine
  • 5-Fluoro-2-(3-{[(5-methylpyrimidin-2-yl)oxy]methyl}piperidin-1-yl)pyrimidine
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