Methyl 1-methylcyclopropyl ketone

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Names

[ CAS No. ]:
1567-75-5

[ Name ]:
Methyl 1-methylcyclopropyl ketone

[Synonym ]:
EINECS 216-369-8
MFCD00010245
1-(1-methylcyclopropyl)ethanone

Chemical & Physical Properties

[ Density]:
0.895 g/mL at 25 °C(lit.)

[ Boiling Point ]:
125-128 °C(lit.)

[ Melting Point ]:
125-128 °C(lit.)

[ Molecular Formula ]:
C6H10O

[ Molecular Weight ]:
98.14300

[ Flash Point ]:
75 °F

[ Exact Mass ]:
98.07320

[ PSA ]:
17.07000

[ LogP ]:
1.37550

[ Vapour Pressure ]:
11.6mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.434(lit.)

[ Storage condition ]:
Flammables area

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R10;R22

[ Safety Phrases ]:
16-29-33

[ RIDADR ]:
UN 1224 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2914299000

Synthetic Route

Precursor & DownStream

Precursor

  • 5-Chloro-3-methylpentan-2-one
  • 3-Acetyl-3-methyltetrahydrofuran-2-one
  • trans-1,2-dibromo-1,2-dimethylcyclobutane
  • 1-Methylcyclopropanecarboxylic acid
  • METHYLLITHIUM
  • 1,4-dimethyl-5-oxabicyclo[2.1.0]pentane
  • 2,3-DIMETHYL-1,3-BUTADIENE
  • Methanol
  • 1-cyclopropyl-1-nitrosourea
  • Acetone

DownStream

  • 1-Methylcyclopropanecarboxylic acid
  • Ethanone, 2-bromo-1-(1-methylcyclopropyl)- (9CI)

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Samarium Diiodide Induced Reactions of Cyclopropyl Ketones: Reductive Ring Cleavage and Dimerization Leading to 1, 8-Diketones-Scope, Limitations, Mechanisms. Aulenta F, et al.

European J. Org. Chem. 2006(7) , 1733-1739, (2006)


More Articles


Related Compounds

  • 1-(1-Methylcyclopropyl)-1-(4-methylphenyl)ethanol
  • methyl 1-adamantyl ketone O-trimethylsilyloxime
  • methyl 1-naphthyl ketone O-methyloxime
  • methyl 1-isoquinolinyl ketone <5-<4-(2-pyridinyl)-1-piperazinyl>-1,3,4-thiadiazol-2-yl>hydrazone
  • methyl-(1-isoquinolylmethyl)-ketone
  • methyl 3-(1-methylcyclopropyl)-3-oxo-propanoate