5-Hexenoic acid

Names

[ CAS No. ]:
1577-22-6

[ Name ]:
5-Hexenoic acid

[Synonym ]:
Hex-5-enoic acid
5-Hexenoic acid
MFCD00046558

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
202.6±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C₆H₁₀O₂

[ Molecular Weight ]:
114.142

[ Flash Point ]:
100.1±13.9 °C

[ Exact Mass ]:
114.068077

[ PSA ]:
37.30000

[ LogP ]:
1.36

[ Vapour Pressure ]:
0.1±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.444

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45-S27

[ RIDADR ]:
3265

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2916190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Hexen-6-ol
3-trimethylsilylcyclohexan-1-one
3-tributylstannylcyclohexan-1-one
Carbon dioxide
1-bromo-4-pentene
2-(trimethylsilylmethyl)cyclopentanone
2-((tributylstannyl)methyl)cyclopentanone
Cyclohexanone
6-nitrohex-1-ene
ETHYLMAGNESIUM BROMIDE

DownStream

5-ethenyldihydro-2(3H)-Furanone
2H-Pyran-2-one,3,4-dihydro-6-methyl-
2-hexen-4-olide
6-Bromohexanoic acid
Cyclohexanone
4-HEXENOIC ACID
3-hexenoic acid
6-Chloro-1-hexene
Glutaric acid
6-(hydroxymethyl)oxan-2-one

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Production of functionalized polyhydroxyalkanoates by genetically modified Methylobacterium extorquens strains.

Microb. Cell Fact. 9 , 70, (2010)

Methylotrophic (methanol-utilizing) bacteria offer great potential as cell factories in the production of numerous products from biomass-derived methanol. Bio-methanol is essentially a non-food substr...

Tertiary aminourea-catalyzed enantioselective iodolactonization.

Angew. Chem. Int. Ed. Engl. 49(40) , 7332-5, (2010)

Synthesis of fluoroalkyl-d-lactones from polyfluoroalkyl iodides and 5-hexenoic acids. Fang X, et al.

J. Fluor. Chem. 129(4) , 280-285., (2008)