Ethyl oxophenylacetate

Suppliers

Names

[ Name ]:
Ethyl oxophenylacetate

[Synonym ]:
ethyl 2-oxo-2-phenylacetate
Ethyl phenylglyoxylate
Ethyl oxophenylacetate
Glyoxylic acid, phenyl-, ethyl ester (8CI)
Ethyloxo(phenyl)acetat
Benzoylformic Acid Ethyl Ester
Phenylglyoxylic Acid Ethyl Ester
Ethyl oxo(phenyl)acetate
ethyl phenyloxoacetate
Glyoxylic acid, phenyl-, ethyl ester
MFCD00009120
ETHYL α-OXOBENZENEACETATE
EINECS 216-504-0
Benzeneacetic acid, α-oxo-, ethyl ester
Ethyl benzoylformate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
256.5±0.0 °C at 760 mmHg

[ Melting Point ]:
97ºC

[ Molecular Formula ]:
C₁₀H₁₀O₃

[ Molecular Weight ]:
178.185

[ Flash Point ]:
111.4±15.9 °C

[ Exact Mass ]:
178.062988

[ PSA ]:
43.37000

[ LogP ]:
1.80

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.513

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2942000000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

ethyl mandelate
Ethyl phenylacetate
ETHYL ALPHA-BROMOPHENYLACETATE
Triphenylboroxin
Ethyl cyanoformate
Phenylboronic acid
1-Ethoxy-2-phenylacetylene
1-(ethoxycarbonyl-1-phenylmethyl)pyridinium bromide
2-(4b-dimethylaminomethylene)-2-phenyl ethyl acetate

DownStream

Difluoro(phenyl)acetic acid
Phenylmaleic anhydride
2-Phenylacrylic acid
1,1-dioxo-3-phenyl-2,3-dihydro-1,2,5-thiadiazol-4-amine
alpha-Cyclopentylmandelic acid
Benzeneacetic acid, a-hydroxy-a-methyl-
2-phenyl-3-aminopropanoic acid
α-Cyclohexylmandelic acid
2,2-difluoro-2-phenylacetonitrile
styrene glycol

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

98% Enantioselectivity in the asymmetric synthesis of a useful chiral building block by heterogeneous method: Enantioselective hydrogenation of ethyl-benzoylformate over cinchona modified Pt/Al₂ O₃ catalysts in the acetic acid. Sutyinszki M, et al.

Catal. Commun. 3(3) , 125-7, (2002)

Preparation of chiral 5-deazaflavin derivatives and their asymmetric reduction of ethyl benzoylformate. Tanaka K, et al.

Tetrahedron Lett. 25(16) , 1741-2, (1984)

ethyl 8-(4-fluorophenyl)-8-oxooctanoate
ETHYL 4-(3,4-DIMETHYLPHENYL)-4-OXOBUTYRATE
ethyl 3-(3-nitrophenyl)-4-oxopent-2-enoate
ETHYL 8-(1-NAPHTHYL)-8-OXOOCTANOATE
ETHYL 2-((TERT-BUTOXYCARBONYL)AMINO)THIAZOLE-5-CARBOXYLATE
ETHYL MORPHOLINE-2-CARBOXYLATE HYDROCHLORIDE
8-Chlorochroman-4-carboxylic acid
2-(5-Chloro-2-methoxyphenyl)-2-methylpropanal
3-Methyl-2-{[1,2,4]triazolo[4,3-a]pyridin-6-yl}butanoic acid
3-Amino-3-(3-chlorophenyl)-N-methylpropanamide
3-bromo-1-triisopropylsilyl-pyrrolo[2,3-b]pyridine-6-sulfonyl chloride
1-(thiazol-4-ylmethyl)pyrazol-4-amine
2-[3-(Methoxymethyl)phenyl]-3-methylbutanoic acid
tert-butyl N-(1-cyanocyclohexyl)-N-methylcarbamate
5-[(2-Chlorophenyl)methyl]-1,3,4-oxadiazole-2-carboxylic acid
5-[(3-Chlorophenyl)methyl]-1,3,4-oxadiazole-2-carboxylic acid

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