2,4,6-Trimethylbenzene-1-sulfonohydrazide

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Names

[ CAS No. ]:
16182-15-3

[ Name ]:
2,4,6-Trimethylbenzene-1-sulfonohydrazide

[Synonym ]:
EINECS 240-319-4
2,4,6-trimethylbenzenesulfonohydrazide
2-Mesitylenesulfonyl Hydrazide
2,4,6-Trimethylbenzenesulfonyl Hydrazide
MFCD00007585

Chemical & Physical Properties

[ Density]:
1.217g/cm3

[ Boiling Point ]:
369.1ºC at 760mmHg

[ Melting Point ]:
112-114 °C (dec.)(lit.)

[ Molecular Formula ]:
C9H14N2O2S

[ Molecular Weight ]:
214.28500

[ Flash Point ]:
177ºC

[ Exact Mass ]:
214.07800

[ PSA ]:
80.57000

[ LogP ]:
2.93580

[ Vapour Pressure ]:
1.21E-05mmHg at 25°C

[ Index of Refraction ]:
1.557

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
R5

[ Safety Phrases ]:
S16-S26-S36

[ RIDADR ]:
UN 1325 4.1/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
4.1

[ HS Code ]:
2935009090

Synthetic Route

Precursor & DownStream

Precursor

  • Ethyl N-[(mesitylsulfonyl)oxy]ethanimidate
  • mesitylene-2-sulfonyl chloride

DownStream

  • Benzene,1,3,5-trimethyl-2-(phenylsulfonyl)-
  • 1,3,5-trimethyl-2-pentylsulfanylsulfonylbenzene
  • N'-Cyclopentylidene-2,4,6-triMethylbenzenesulfonohydrazide
  • N-[(2-bromo-1-phenyl-ethylidene)amino]-2,4,6-trimethyl-benzenesulfonamide

Customs

[ HS Code ]: 2935009090

[ Summary ]:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

Articles

Concise Synthesis of 1, 4a-Bifunctionalised Decalin Building Blocks by CH Activation of Decalin. Uosis-Martin M, et al.

Synlett 2011(15) , 2211-13, (2011)

A model system for the synthesis of complanadine alkaloids by "diverted Kondrat'eva" oxazole-olefin cycloaddition.

J. Org. Chem. 78(12) , 6253-63, (2013)

A synthetic approach to complanadine alkaloids is described which employs a Kondrat'eva reaction to construct the pyridine rings. The viability of this approach is demonstrated by its application to a...


More Articles


Related Compounds

  • 2,4,6-trimethylbenzene-1,3-dicarbonyl chloride
  • 2,4,6-trimethylbenzene-1,3-dicarbaldehyde
  • 2,4,6-trimethylbenzene-1,3,5-tricarbaldehyde
  • 2,4,6-trimethylbenzene-1,3,5-tricarbonitrile
  • 2,4,6-Trimethylbenzene-1,3-diamine
  • Trimethylphloroglucinol
  • (2S)-2-(2-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,3-thiazol-4-yl}acetamido)pentanoic acid
  • 2-(2-{[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)butanamido]methyl}-1,3-thiazol-4-yl)acetic acid
  • 2-(2-{[4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)but-2-ynamido]methyl}-1,3-thiazol-4-yl)acetic acid
  • 2-[2-(2-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,3-thiazol-4-yl}acetamido)ethoxy]acetic acid
  • 4-(2-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,3-thiazol-4-yl}acetamido)-2-hydroxybutanoic acid
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-[3-(2-hydroxypropan-2-yl)piperidin-1-yl]-4-oxobutanoic acid
  • 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3-[methyl(2-sulfamoylethyl)carbamoyl]propanoic acid
  • 4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-[methyl(2-sulfamoylethyl)carbamoyl]butanoic acid
  • 2-{[(2S)-3-(dimethylamino)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanamido]methyl}cyclopropane-1-carboxylic acid
  • 2-[(3R)-3-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-N-methylpentanamido]butanoic acid
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