N-methyl-N-pyridin-2-ylnitrous amide

Names

[ CAS No. ]:
16219-98-0

[ Name ]:
N-methyl-N-pyridin-2-ylnitrous amide

[Synonym ]:
N-methyl-N-nitrosopyridin-2-amine
2-N-nitrosomethylaminopyridine
2-Nitrosomethylaminopyridine
methyl-nitroso-pyridin-2-yl-amine
N-Methyl-N-nitroso-2-aminopyridine
N-Nitroso-N-methyl-2-aminopyridine
Pyridine,2-nitrosomethylamino

Chemical & Physical Properties

[ Density]:
1.17g/cm3

[ Boiling Point ]:
286.6ºC at 760mmHg

[ Molecular Formula ]:
C6H7N3O

[ Molecular Weight ]:
137.13900

[ Flash Point ]:
127.1ºC

[ Exact Mass ]:
137.05900

[ PSA ]:
45.56000

[ LogP ]:
1.19920

[ Vapour Pressure ]:
0.00262mmHg at 25°C

[ Index of Refraction ]:
1.569

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UT6386000
CHEMICAL NAME :
Pyridine, 2-nitrosomethylamino-
CAS REGISTRY NUMBER :
16219-98-0
BEILSTEIN REFERENCE NO. :
0118228
LAST UPDATED :
199612
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C6-H7-N3-O
MOLECULAR WEIGHT :
137.16
WISWESSER LINE NOTATION :
T6NJ BN1&NO

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
60 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - acute pulmonary edema Gastrointestinal - ulceration or bleeding from stomach Gastrointestinal - ulceration or bleeding from large intestine
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
250 mg/kg/50W-I
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Gastrointestinal - tumors Liver - tumors

MUTATION DATA

TYPE OF TEST :
Host-mediated assay
TEST SYSTEM :
Rodent - mouse Bacteria - Escherichia coli
DOSE/DURATION :
60 mg/kg
REFERENCE :
CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 3,415,1982

Synthetic Route

Precursor & DownStream

Precursor

  • 2-(Methylamino)pyridine

DownStream

  • 2-(1-methylhydrazino)pyridine

Related Compounds

  • N-METHYL-N-PYRIDIN-2-YLETHANE-1,2-DIAMINE
  • N-METHYL-N-PYRIDIN-2-YLPROPANE-1,3-DIAMINE
  • N-Methyl-N-(pyridin-2-yl)pivalamide
  • N-METHYL-N-PYRIDIN-2-YL-4-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-BENZAMIDE
  • N-methyl-N-pyridin-2-ylpropanamide
  • N-methyl-N-pyridin-2-ylmethanesulfonamide
  • (2S)-2-(4,4-Dimethyloxolan-2-yl)propan-1-amine
  • Saponarioside M
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 2-(2-methyl-5-nitroanilino)-4-pyridin-3-yl-1H-pyrimidin-6-one
  • 5-(chloromethyl)-3-[3-(3,4-dimethoxyphenyl)-1,2,4-oxadiazol-5-yl]-2-(methylsulfanyl)-4H,7H-pyrazolo[1,5-a]pyrimidin-7-one
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide