1-Benzylpyrrole-2,5-dione

Names

[ Name ]:
1-Benzylpyrrole-2,5-dione

[Synonym ]:
1H-Pyrrole-2,5-dione, 1-(phenylmethyl)-
1-Benzyl-1H-pyrrole-2,5-dione
1-benzyl-2,5-dihydro-1H-pyrrole-2,5-dione
EINECS 216-631-1
N-Benzyl maleimide
1-benzylpyrrole-2,5-dione
MFCD00014540

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
338.8±21.0 °C at 760 mmHg

[ Melting Point ]:
70 °C(lit.)

[ Molecular Formula ]:
C₁₁H₉NO₂

[ Molecular Weight ]:
187.19

[ Flash Point ]:
157.9±14.4 °C

[ Exact Mass ]:
187.063324

[ PSA ]:
37.38000

[ LogP ]:
1.78

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.625

[ Water Solubility ]:
Insoluble

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R20/21;R25;R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 1759 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
2925190090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Maleic anhydride
Benzylamine
2-Butenoic acid,4-oxo-4-[(phenylmethyl)amino]-, (2Z)-
Maleimide
Benzyl alcohol
N-benzyl-3-chloropyrrolidine-2,5-dione
2-nitrobenzyl-3α,4,7,7α-tetrahydro-4,7-epoxy-1H-isoindole-1,3(2H)-dione
Benzaldoxime

DownStream

(1R,5S)-3-BENZYL-6-NITRO-3-AZABICYCLO[3.1.0]HEXANE
TERT-BUTYL ((1R,5S,6S)-3-BENZYL-3-AZABICYCLO[3.1.0]HEXAN-6-YL)CARBAMATE
2-Benzyloctahydropyrrolo[3,4-c]pyrrole
3-Benzyl-3-azabicyclo[3.1.0]hexane-2,4-dione
1-benzyl-3-methylene-pyrrolidine-2,5-dione
3-Benzyl-3-azabicyclo[3.1.0]hexan-6-amine
2,5-DIBENZYLTETRAHYDROPYRROLO[3,4-C]PYRROLE-1,3(2H,3AH)-DIONE
6-Amino-3-benzyl-3-azabicyclo[3.1.0]hexane
2-Benzyloctahydropyrrolo[3,4-c]pyrrole
N-Phenylmethyl succinimide

Customs

[ HS Code ]: 2925190090

[ Summary ]:
2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Construction of a single-chain Fv from an antibody which catalyses a Diels Alder cycloaddition.

Biochem. Soc. Trans. 24(2) , 313S, (1996)

Parallel synthesis and purification using anthracene-tagged substrates.

Org. Lett. 2(22) , 3509-12, (2000)

[reaction: see text] A new strategy for the synthesis and purification of synthetic intermediates is described using anthracene-tagged ester substrates in conjunction with an N-benzylmaleimide resin. ...

Copolymerization of optically active N-(l-menthoxycarbonylmethyl) maleimide with N-phenyl-or N-benzylmaleimide. Kagawa K, et al.

Polymer 36(5) , 941-48, (1995)

1-benzylpyrrole-2,5-dione,ethenoxyethene
1-triethylstannylpyrrole-2,5-dione
1-trimethylstannylpyrrolidine-2,5-dione
1-hexadecylpyrrole-2,5-dione
1-fluoropyrrolidine-2,5-dione
1-methylpiperazine-2,5-dione
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
methyl 4-((3-(2,5-dimethoxyphenyl)-1-methyl-1H-pyrazole-5-carboxamido)methyl)piperidine-1-carboxylate
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide