(3R,4R)-1-Benzyl-3,4-pyrrolidinediol

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Names

[ CAS No. ]:
163439-82-5

[ Name ]:
(3R,4R)-1-Benzyl-3,4-pyrrolidinediol

[Synonym ]:
3,4-Pyrrolidinediol, 1-(phenylmethyl)-, (3R,4R)-
(3R,4R)-1-Benzyl-3,4-pyrrolidinediol
(3R,4R)-1-Benzylpyrrolidine-3,4-diol
(3R,4R)-(-)-1-Benzyl-3,4-pyrrolidindiol
(3R,4R)-(−)-1-Benzyl-3,4-pyrrolidinediol
MFCD01073894

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
356.2±12.0 °C at 760 mmHg

[ Melting Point ]:
95-101ºC

[ Molecular Formula ]:
C11H15NO2

[ Molecular Weight ]:
193.242

[ Flash Point ]:
195.1±18.2 °C

[ Exact Mass ]:
193.110275

[ PSA ]:
43.70000

[ LogP ]:
0.26

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.634

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29339900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (3S)-BOC-3-AMINO-4-PHENYL-2-BUTANONE
  • 1,2,3,4-Butanetetrol,1,4-bis(4-methylbenzenesulfonate), (2R,3R)-
  • Benzylamine
  • Boron trifluoride etherate
  • (3R)-3-METHYL-4-(TERT-BUTY)DIPHENYLSILYLOXY)BUTANAL
  • D-Tartaric acid

DownStream

  • (S,S)-N-BENZYL-3,4-TRANS-DIAMINOPYRROLIDINE
  • (S,S)-3-CBZ-3,6-DIAZABICYCLO[3.2.0]HEPTANE
  • (3S,4R,5R,6S)-4-OXO-PENTANOICACID4,5-BIS-BENZYLOXY-6-BENZYLOXYMETHYL-2-P-TOLYLSULFAN

Articles

R. Ballini et al.

J. Org. Chem. 57 , 1316, (1992)

S. Cicchi et al.

J. Chem. Soc. Perkin Trans. I , 367, (1998)


More Articles

Related Compounds

  • (3R,4R)-1-Benzyl-3,4-pyrrolidinediol
  • (3R,4R)-1-benzyl-3,4-bis(propan-2-ylsulfanyl)pyrrolidine
  • 3-[(3R,4R)-1-benzyl-3,4-dimethylpiperidin-4-yl]benzamide
  • (2S,3R,4R)-1-benzyl-3,4-bis(benzyloxy)-2-(benzyloxymethyl)piperidine
  • (3R)-3-METHYL-4-(TERT-BUTY)DIPHENYLSILYLOXY)BUTANAL
  • (R,R)-ETHYLENEBIS(4,5,6,7-TETRAHYDRO-1-INDENYL)DIFLUOROTITANIUM(IV)