Iron(III) meso-tetraphenylporphine chloride

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Names

[ CAS No. ]:
16456-81-8

[ Name ]:
Iron(III) meso-tetraphenylporphine chloride

[Synonym ]:
Iron(III) meso-tetraphenylporphine chloride
iron(3+),5,10,15,20-tetraphenyl-21,22-dihydroporphyrin,trichloride
MFCD00012152

Chemical & Physical Properties

[ Melting Point ]:
300 °C

[ Molecular Formula ]:
C44H28ClFeN4

[ Molecular Weight ]:
704.01800

[ Exact Mass ]:
703.13500

[ PSA ]:
34.58000

[ LogP ]:
7.12480

[ Appearance of Characters ]:
crystal | purple

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong acids.

[ Water Solubility ]:
Insoluble in water.

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Precursor & DownStream

Precursor

  • tetraphenylporphyrin
  • Fe(tetraphenylporphyrinate)C6H5
  • Pyrrole
  • Benzaldehyde
  • (tetraphenylporphyrin)Fe(CH3)
  • IRON (III) MESO-TETRAPHENYLPORPHINE-MU-OXO DIMER
  • CHLORIDE STANDARD
  • 3-(thiophen-3-ylmethyl)thiophene

DownStream

  • 5,10,15,20-tetraphenyl-21h,23h-porphine iron(iii) chloride

Articles

A possible model of hemoprotein-fatty acid peroxide complex demonstrated by electron spin resonance.

Biochem. Biophys. Res. Commun. 166(2) , 924-30, (1990)

Coordination reaction between linolenic-acid-hydroperoxide (LHPO) and chloro(5, 10, 15, 20-tetraphenyl)-porphyrinato iron (III), Fe(III)TPPCl, was investigated by means of ESR. ESR spectra of the ferr...

Structure of monoclinic chloro(meso-tetraphenylporphyrinato)iron(III).

Acta Crystallogr. C 45 ( Pt 8) , 1214-6, (1989)

[FeCl(C44H28N4)], Mr = 704.03, monoclinic, P21/n, a = 10.254 (2), b = 15.969 (3), c = 20.810 (4) A, beta = 90.48 (2) degree, V = 3407.7 A3, Z = 4, Dx = 1.37 g cm-3, Mo K alpha, lambda = 0.71073 A, mu ...


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  • 3-Bromo-4-fluoroisopropylbenzene
  • 3-Bromo-2,4,6-trifluorobenzaldehyde
  • 2-Bromo-6-chloro-4-fluorobenzenethiol
  • 4-Bromo-5-fluoro-2-methylbenzenesulfonyl chloride
  • 2-Chloro-4-fluoro-5-methylbenzenethiol
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