(s)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane

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Names

[ CAS No. ]:
16495-03-7

[ Name ]:
(s)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane

[Synonym ]:
(S)-1-Benzyl-2,3-O-isopropylidene Glycerol
MFCD00043000
(S)-4-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolane
(4S)-2,2-dimethyl-4-(phenylmethoxymethyl)-1,3-dioxolane
(S)-4-Benzyloxymethyl-2,2-dimethyl-1,3-dioxolane

Chemical & Physical Properties

[ Density]:
1.050 g/mL at 20 °C(lit.)

[ Boiling Point ]:
79-80 °C0.05 mm Hg(lit.)

[ Molecular Formula ]:
C13H18O3

[ Molecular Weight ]:
222.28000

[ Flash Point ]:
100 °C

[ Exact Mass ]:
222.12600

[ PSA ]:
27.69000

[ LogP ]:
2.35470

[ Index of Refraction ]:
n20/D 1.496

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (S)-(+)-Solketal
  • Benzyl chloride
  • Benzyl bromide
  • 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol
  • 2-((Benzyloxy)methyl)oxirane
  • 2,2-Dimethoxypropane
  • Solketal
  • (2R,7R)-2,7-di-O-acetyl-1,8-di-O-benzyl-23,5E-octadiene-1,2,7,8-tetraol
  • (R)-(+)-3-Benzyloxy-1,2-propanediol

DownStream

  • (S)-(+)-Solketal
  • (R)-(-)-Benzyl glycidyl ether
  • (S)-(+)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
  • (S)-1-(BENZYLOXY)-3-(TRITYLOXY)PROPAN-2-OL
  • (R)-2,3-BIS(BENZYLOXY)PROPAN-1-OL

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

J. Oehlenschläger, G. Gercken

Lipids 13 , 557, (1978)

B.T. Golding, P.V. Ioannou

Synthesis , 423, (1977)

G. Hirth, R. Barner

Helv. Chim. Acta 65 , 1059, (1982)


More Articles

Related Compounds

  • (S)-4-[(4-methoxybenzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane
  • (R)-4-BENZYLOXYMETHYL-2,2-DIMETHYL-1,3-DIOXOLANE
  • (r)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane
  • (2S,3S)-(-)-bis(dibenzyloxymethyl)-2,2-dimethyl-1,3-dioxolane
  • (4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde
  • (S)-(-)-4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 3-Cyclohexyl-2-hydroxy-3-methylbutanoic acid
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide