(s)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane

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Names

[ Name ]:
(s)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane

[Synonym ]:
(S)-1-Benzyl-2,3-O-isopropylidene Glycerol
MFCD00043000
(S)-4-((Benzyloxy)methyl)-2,2-dimethyl-1,3-dioxolane
(4S)-2,2-dimethyl-4-(phenylmethoxymethyl)-1,3-dioxolane
(S)-4-Benzyloxymethyl-2,2-dimethyl-1,3-dioxolane

Chemical & Physical Properties

[ Density]:
1.050 g/mL at 20 °C(lit.)

[ Boiling Point ]:
79-80 °C0.05 mm Hg(lit.)

[ Molecular Formula ]:
C₁₃H₁₈O₃

[ Molecular Weight ]:
222.28000

[ Flash Point ]:
100 °C

[ Exact Mass ]:
222.12600

[ PSA ]:
27.69000

[ LogP ]:
2.35470

[ Index of Refraction ]:
n20/D 1.496

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Safety Phrases ]:
S23-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

(S)-(+)-Solketal
Benzyl chloride
Benzyl bromide
1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol
2-((Benzyloxy)methyl)oxirane
2,2-Dimethoxypropane
Solketal
(2R,7R)-2,7-di-O-acetyl-1,8-di-O-benzyl-23,5E-octadiene-1,2,7,8-tetraol
(R)-(+)-3-Benzyloxy-1,2-propanediol

DownStream

(S)-(+)-Solketal
(R)-(-)-Benzyl glycidyl ether
(S)-(+)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
(S)-1-(BENZYLOXY)-3-(TRITYLOXY)PROPAN-2-OL
(R)-2,3-BIS(BENZYLOXY)PROPAN-1-OL

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

J. Oehlenschläger, G. Gercken

Lipids 13 , 557, (1978)

B.T. Golding, P.V. Ioannou

Synthesis , 423, (1977)

G. Hirth, R. Barner

Helv. Chim. Acta 65 , 1059, (1982)

(S)-4-[(4-methoxybenzyloxy)methyl]-2,2-dimethyl-1,3-dioxolane
(R)-4-BENZYLOXYMETHYL-2,2-DIMETHYL-1,3-DIOXOLANE
(r)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane
(2S,3S)-(-)-bis(dibenzyloxymethyl)-2,2-dimethyl-1,3-dioxolane
(4S,5R)-4-benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-5-carboxaldehyde
(S)-(-)-4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane
1-tert-butyl-5-(1-methyl-1H-pyrazol-5-yl)-1H-1,2,3-triazole-4-carboxylic acid
1-butyl-5-(1-methyl-1H-pyrazol-5-yl)-1H-1,2,3-triazole-4-carboxylic acid
1-(2,2-difluoroethyl)-5-(1-methyl-1H-pyrazol-5-yl)-1H-1,2,3-triazole-4-carboxylic acid
5-chloro-1-methyl-3-(1-methyl-1H-pyrazol-5-yl)-1H-pyrazole-4-carboxylic acid
2-{[1-methyl-3-(1-methyl-1H-pyrazol-5-yl)-1H-pyrazol-5-yl]sulfanyl}acetic acid
[5-chloro-1-methyl-3-(1-methyl-1H-pyrazol-5-yl)-1H-pyrazol-4-yl]methanol
[5-chloro-1-ethyl-3-(1-methyl-1H-pyrazol-5-yl)-1H-pyrazol-4-yl]methanol
1-(3-Tert-butylphenyl)-2,2-difluoroethan-1-ol
5-(4-Bromo-5-methoxythiophen-2-yl)-1,2-oxazol-3-amine
Ethyl 4-amino-3-cyclopentylbutanoate

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