(S)-(+)-Benzyl glycidyl ether

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Names

[ Name ]:
(S)-(+)-Benzyl glycidyl ether

[Synonym ]:
(2S)-2-[(Benzyloxy)methyl]oxirane
(S)-1-(Benzyloxy)-2,3-epoxypropane
Benzyl S-(+)-glycidyl ether
(S)-(+)-2-(Benzyloxymethyl)oxirane
MFCD00054428
Benzyl (S)-(+)-Glycidyl Ether
(S)-(+)-1-Benzyloxy-2,3-epoxypropane
(2S)-2-(phenylmethoxymethyl)oxirane
Oxirane, 2-[(phenylmethoxy)methyl]-, (2R)-
(S)-2-((Benzyloxy)methyl)oxirane
Oxirane, 2-[(phenylmethoxy)methyl]-, (2S)-
(2R)-2-[(Benzyloxy)methyl]oxirane
(R)-1-(Benzyloxy)-2,3-epoxypropane
(r)-benzyloxymethyl-oxirane
( S)-(+)-2-(benzyloxymethyl)-oxirane

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
252.7±15.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₂O₂

[ Molecular Weight ]:
164.201

[ Flash Point ]:
100.9±19.9 °C

[ Exact Mass ]:
164.083725

[ PSA ]:
21.76000

[ LogP ]:
2.04

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.535

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX2860020

CHEMICAL NAME :: Propane, 1-(benzyloxy)-2,3-epoxy-, (R)-

CAS REGISTRY NUMBER :: 16495-13-9

LAST UPDATED :: 199410

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H12-O2

MOLECULAR WEIGHT :: 164.22

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Mutation test systems - not otherwise specified

TYPE OF TEST :: Cytogenetic analysis

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
TX2860030

[ HS Code ]:
2910900090

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Bioresolution of benzyl glycidyl ether using whole cells of Bacillus alcalophilus.

J. Basic Microbiol. 52(4) , 383-9, (2012)

The incubation of whole Bacillus alcalophilus cells grown on a mineral supplemented medium (MSM) containing 1% (w/v) sucrose as carbon source, 1.2% (w/v) tryptone as nitrogen source at pH 6.5 and temp...

Metal-mediated cyclization of aryl and benzyl glycidyl ethers: a complete scenario.

J. Am. Chem. Soc. 130(50) , 16838-9, (2008)

Enantiomerically pure aryl and benzyl glycidyl ethers undergo stereospecific cyclizations leading to 3-chromanols or to tetrahydrobenzo[c]oxepin-4-ols under mild conditions in the presence of a cataly...

Enantioselective total synthesis of (+)-gigantecin: exploiting the asymmetric glycolate aldol reaction.

J. Am. Chem. Soc. 126(40) , 12790-1, (2004)

The enantioselective synthesis of the potent, selective, cytotoxic, annonaceous acetogenin, (+)-gigantecin, has been completed. An asymmetric glycolate aldol serves to establish the stereocenters at C...