2,4,5-Trifluorobenzaldehyde

Names

[ Name ]:
2,4,5-Trifluorobenzaldehyde

[Synonym ]:
2,4,5-Trifluorobenzaldehyde
MFCD00061196
Benzaldehyde,2,4,5-trifluoro
Benzaldehyde, 2,4,5-trifluoro-
2,4,5-trifluoro benzaldehyde
VHR BF DF EF

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
179.1±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C₇H₃F₃O

[ Molecular Weight ]:
160.093

[ Flash Point ]:
51.6±17.4 °C

[ Exact Mass ]:
160.013596

[ PSA ]:
17.07000

[ LogP ]:
1.92

[ Vapour Pressure ]:
1.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.492

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 1993 3/PG 1

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2913000090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

(2,4,5-Trifluorphenyl)methanol
2-Phenylbenzofuran
methoxymethanol
methyl (2r)-2-[(tert-butoxycarbonyl)amino]-3-(2,4,5-trifluorophenyl)propanoate

Customs

[ HS Code ]: 2913000090

[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

Articles

Synthesis of fluorinated benzophenones, xanthones, acridones, and thioxanthones by iterative nucleophilic aromatic substitution.

J. Org. Chem. 77(1) , 473-81, (2012)

Fluorination of fluorophores can substantially enhance their photostability and improve spectroscopic properties. To facilitate access to fluorinated fluorophores, bis(2,4,5-trifluorophenyl)methanone ...

Aminol initiated Prins cyclization for the synthesis of octahydro-1H-pyrano [3, 4-c] pyridine and hexahydro-1H-furo [3, 4-c] pyrrole derivatives.

Tetrahedron Lett. 55(34) , 4817-4821, (2014)

(E)-4-Methoxy-N'-(2, 4, 5-trifluorobenzylidene) benzohydrazide monohydrate. Maheswari R, et al.

IUCrJ 1(5) , x160846., (2016)

2,4,5-Trifluorobenzaldehyde oxime
3-chloro-2,4,5-trifluorobenzaldehyde
3-Chloro-2,4,5-trifluorobenzaldehyde
2-(4,5-DICHLORO-1H-IMIDAZOL-1-YL)-N-HYDROXYACETAMIDE
2,4,5-Trimethylbenzoic Acid
(2,4,5-trichlorophenyl) 2,2,2-trichloroacetate
(E)-4-(Dimethylamino)-N-[1-[3-(dimethylsulfamoyl)phenyl]ethyl]but-2-enamide
(E)-N-(2,3-Dihydro-1,4-benzodioxin-5-ylmethyl)-4-(dimethylamino)-N-ethylbut-2-enamide
(2E)-4-(dimethylamino)-N-{1-[(1,3-thiazol-4-yl)methyl]piperidin-4-yl}but-2-enamide
(2E)-N-(2,3-dihydro-1H-inden-2-yl)-4-(dimethylamino)-N-[(2-fluorophenyl)methyl]but-2-enamide
(E)-N-(2-Cyanoethyl)-4-(dimethylamino)-N-(oxolan-3-ylmethyl)but-2-enamide
(E)-4-(Dimethylamino)-N-[1-(2-methoxyphenyl)-2-methylpropan-2-yl]but-2-enamide
(2E)-4-(dimethylamino)-N-[3-(4-fluorophenoxy)propyl]-N-(2-methoxyethyl)but-2-enamide
(2E)-N-[2-(5-tert-butyl-1,2,4-oxadiazol-3-yl)propan-2-yl]-4-(dimethylamino)but-2-enamide
(E)-4-(Dimethylamino)-N-[[2-(3-methylphenoxy)phenyl]methyl]but-2-enamide
(2E)-4-(dimethylamino)-N-({2-[ethyl(methyl)amino]pyridin-4-yl}methyl)but-2-enamide

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