BIS(2,4-DINITROPHENYL) OXALATE

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Names

[ Name ]:
BIS(2,4-DINITROPHENYL) OXALATE

[Synonym ]:
MFCD00010712
2,4-Dinitrophenyl oxalate
Ethanedioic acid, bis(2,4-dinitrophenyl) ester
Oxalic acid bis(2,4-dinitrophenyl) ester
2,4-Dinitrophenyloxalat
BIS(2,4-DINITROPHENYL) OXALATE
bis(2,4-dinitrophenyl)oxalate
DNPO

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
605.1±55.0 °C at 760 mmHg

[ Melting Point ]:
189-190 °C(lit.)

[ Molecular Formula ]:
C₁₄H₆N₄O₁₂

[ Molecular Weight ]:
422.217

[ Flash Point ]:
265.9±33.5 °C

[ Exact Mass ]:
421.998230

[ PSA ]:
235.88000

[ LogP ]:
3.51

[ Vapour Pressure ]:
0.0±1.7 mmHg at 25°C

[ Index of Refraction ]:
1.674

[ Storage condition ]:
−20°C

[ Stability ]:
Stable. Incompatible with strong oxidizing agents, strong bases.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1325.0

[ WGK Germany ]:
3

[ Hazard Class ]:
4.1

[ HS Code ]:
2917119000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2917119000

[ Summary ]:
2917119000 oxalic acid salts and esters VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Determination of fluorophor-labeled compounds based on peroxyoxalate chemiluminescence.

Anal. Biochem. 136 , 277, (1984)

Fluorophor-labeled compounds are determined by adding an aromatic oxalate ester and hydrogen peroxide and measuring the resulting chemiluminescence (CL). Rhodamine B is excited more efficiently than 2...

Optimization of an HPLC peroxyoxalate chemiluminescence detection system for some dansyl amino acids.

J. Biolumin. Chemilumin. 5(1) , 13-23, (1990)

Bis(2,4,6-trichlorophenyl) oxalate (TCPO)-hydrogen-peroxide-generated chemiluminescence (CL) of four dansyl amino acids has been used as a model system for the optimization of a detection system in re...

Kinetics and Mechanism of the Nucleophilic Substitution Reaction of Imidazole with Bis(2,4,6-trichlorophenyl) Oxalate and Bis(2,4-dinitrophenyl) Oxalate.

J. Org. Chem. 61(8) , 2657-2663, (1996)

The kinetics of the imidazole-catalyzed decomposition of bis(2,4,6-trichlorophenyl) oxalate (TCPO) and bis(2,4-dinitrophenyl) oxalate (DNPO) was investigated by the stopped-flow technique. Pseudo-firs...