2,4-Dinitrobenzenesulfonyl chloride

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Names

[ Name ]:
2,4-Dinitrobenzenesulfonyl chloride

[Synonym ]:
Benzenesulfonyl chloride, 2,4-dinitro-
4-NO2-2-Nos-Cl
2,4-Dinitrobenzenesulfonyl chloride
Benzenesulfonyl chloride,2,4-dinitro
2,4-dinitrobenzylsulfonyl chloride
DNBS-chloride
2,4-dinitrophenylsulfonyl chloride
2,4-dinitrobenzene-sulfonyl chloride
2,4-Dinitrobenzene-1-sulfonyl chloride
EINECS 216-749-3
MFCD00007431
2,4-Dinitrobenzenesulphonyl chloride

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
418.1±35.0 °C at 760 mmHg

[ Melting Point ]:
101-103 °C(lit.)

[ Molecular Formula ]:
C₆H₃ClN₂O₆S

[ Molecular Weight ]:
266.616

[ Flash Point ]:
206.6±25.9 °C

[ Exact Mass ]:
265.940033

[ PSA ]:
134.16000

[ LogP ]:
2.14

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.618

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H340-H350-H373

[ Precautionary Statements ]:
P201-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S53-S26-S36/37/39-S45-S62

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Benzenamine,2-[(2,4-dinitrophenyl)thio]-
1-(4-chlorophenyl)sulfanyl-2,4-dinitrobenzene
2,4-Dinitrophenol
N'-(2,4-dinitrophenyl)propane-1,3-diamine
2,4-Dinitrophenyl phenyl sulfide
Benzenamine,N-butyl-2,4-dinitro-
2,4-Dinitrophenylhydrazine
4-Nitroacetanilide
L-Cysteine,S-(2,4-dinitrophenyl)-
2-(2,4-dinitroanilino)benzoic acid

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Synthesis of _-Glycosyl Amides from N-Glycosyl Dinitrobenzenesulfonamides.

J. Carbohydr. Chem. 31(4-6) , 353-370, (2012)

The N-glycosyl-2,4-dinitrobenzenesulfonamides were accessed via benzoyl-protected _-glycosyl azides. The azides were reduced with Adams' catalyst to the corresponding amines. The glycosylamines were s...

Peptide nucleic acid probes with charged photocleavable mass markers: Towards PNA-based MALDI-TOF MS genetic analysis.

Artif. DNA PNA XNA 1(1) , 27-35, (2010)

Halogen-labelled peptide organic acid (HPOA) monomers have been synthesised and incorporated into sequence-specific peptide nucleic acid (PNA) probes. Three different types of probe have been prepared...