8-Bromoquinoline

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Names

[ CAS No. ]:
16567-18-3

[ Name ]:
8-Bromoquinoline

[Synonym ]:
Quinoline, 8-bromo-
quinolin-8-yl bromide
MFCD00191859
8-Brom-chinolin
8-BROMQUINOLINE
Quinoline,8-bromo
8-Bromoquinoline

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
303.0±0.0 °C at 760 mmHg

[ Melting Point ]:
58-59 °C

[ Molecular Formula ]:
C9H6BrN

[ Molecular Weight ]:
208.055

[ Flash Point ]:
132.8±19.8 °C

[ Exact Mass ]:
206.968353

[ PSA ]:
12.89000

[ LogP ]:
2.51

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.674

[ Storage condition ]:
Refrigerator (+4°C)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Glycerol
  • 2-Bromoaniline
  • 8-Aminoquinoline
  • leucoline
  • 1,2,3,4-tetrahydroquinoline-8-sulfonic acid
  • Water
  • Bromine

DownStream

  • 8-Quinolinecarbonitrile
  • Quinoline-8-carbaldehyde
  • 8-Bromo-3-iodoquinoline
  • leucoline
  • 3H,5H-Benzo[ij]quinolizin-3-one
  • 3-quinolin-8-yl-propenal
  • 8,8'-biquinolinyl
  • Quinoline-8-carboxylic acid
  • Quinolinic acid

Customs

[ HS Code ]: 2933499090

[ Summary ]:
2933499090. other compounds containing in the structure a quinoline or isoquinoline ring-system (whether or not hydrogenated), not further fused. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Reactivity of the bifunctional ambiphilic molecule 8-(dimesitylboryl)quinoline: hydrolysis and coordination to Cu(I), Ag(I) and Pd(II).

Dalton Trans. 39(45) , 11081-90, (2010)

The ambiphilic molecule 8-(dimesitylboryl)quinoline (1) was synthesized by treatment of 8-bromoquinoline or 8-iodoquinoline with n-BuLi followed by dimesitylboronfluoride. Hydrolysis of 1 is unusually...

Direct synthesis of tricyclic 5H-pyrido[3,2,1-ij]quinolin-3-one by domino palladium catalyzed reaction.

Org. Biomol. Chem. 4(20) , 3760-2, (2006)

Unexpectedly, the palladium catalyzed coupling reaction of acrolein with 8-bromoquinoline gave 5H-pyrido[3,2,1-ij]quinolin-3-one in a single step.

Facile synthesis of 8-substituted quinolines. Suggs JW and Pearson GDN.

J. Org. Chem. 45(8) , 1514-15, (1980)


More Articles

Related Compounds

  • 8-Bromoquinoline,HCl
  • 8-Bromoquinoline-4-ol
  • 8-bromoquinoline N-oxide
  • 6-nitro-8-bromoquinoline
  • 5-Amino-8-bromoquinoline
  • 3-amino-8-bromoquinoline
  • (1R,3aR,4S,7aR)-1-[(1R)-1,5-Dimethylhexyl]octahydro-7a-methyl-1H-inden-4-yl 2-chlorobenzoate
  • 3-(3-Chlorophenyl)-5-(2,4-dichlorophenyl)-1,2,4-oxadiazole
  • (2Z)-N-Acetyl-2,3-didehydro-3-(2-naphthalenyl)alanyl-N-[(1S,2E)-4-ethoxy-3-methyl-1-(1-methylethyl)-4-oxo-2-buten-1-yl]-3-methyl-L-valinamide
  • 1-(1-(3-(4-Cyanophenyl)propanoyl)azetidin-3-yl)piperidine-4-carboxamide
  • 3-(4-(6,7-dihydrothieno[3,2-c]pyridin-5(4H)-yl)piperidine-1-carbonyl)-1-methylpyridin-2(1H)-one
  • benzo[d]thiazol-2-yl(4-(6,7-dihydrothieno[3,2-c]pyridin-5(4H)-yl)piperidin-1-yl)methanone
  • 1-(4-(6,7-dihydrothieno[3,2-c]pyridin-5(4H)-yl)piperidin-1-yl)-2-((4-fluorophenyl)thio)ethanone
  • 4-[4-(Quinolin-2-Yl)-1h-1,2,3-Triazol-1-Yl]phenol
  • 4-{4-[6-(2-Methoxyethoxy)quinolin-2-Yl]-1h-1,2,3-Triazol-1-Yl}phenol
  • Norbolethone, (-)-