3,4,7,8-Tetramethyl-1,10-phenanthroline

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Names

[ CAS No. ]:
1660-93-1

[ Name ]:
3,4,7,8-Tetramethyl-1,10-phenanthroline

[Synonym ]:
3,4,7,8-tetramethylpyridino[3,2-h]quinoline
3,4,7,8-Tetramethyl-1,10-phenanthroline
EINECS 216-762-4
3,4,7,8-tmphen
3,4,7,8-Me4phen
3,4,7,8-tetramethyl-phen
1,10-Phenanthroline,3,4,7,8-tetramethyl
MFCD00004974
1,10-Phenanthroline, 3,4,7,8-tetramethyl-
3,4,7,8-Tetramethyl-1, 10-phenanthroline
3,4,7,8-tetra-methyl-1,10-phenanthroline

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
435.2±40.0 °C at 760 mmHg

[ Melting Point ]:
277-280 °C(lit.)

[ Molecular Formula ]:
C16H16N2

[ Molecular Weight ]:
236.312

[ Flash Point ]:
192.6±18.6 °C

[ Exact Mass ]:
236.131348

[ PSA ]:
25.78000

[ LogP ]:
3.62

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.662

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S36/37/39-S26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 8-amino-3,4-dimethylquinoline
  • 2-Butanone,4-hydroxy-3-methyl-
  • o-Phenylenediamine
  • 3,4-dimethyl-8-nitroquinoline
  • 2-Nitroaniline

DownStream

  • 3,4,7,8-tetramethyl-1-oxido-1,10-phenanthrolin-1-ium
  • 1,3-dimethyl-5-phenylmethoxybenzene
  • 5,5,5,5-tetrachloro-1,2,8,9-tetramethyl-5H-5l6-[1,3,2]diazastannolo[1,5,4,3-lmn][1,10]phenanthroline

Articles

Cytotoxic platinum(II) intercalators that incorporate 1R,2R-diaminocyclopentane.

Dalton Trans. 42(4) , 918-26, (2013)

Twelve metallointercalators of the type [Pt(I(L))(A(L))](2+), where A(L) is either the R,R or S,S enantiomer of 1,2-diaminocyclopentane (DACP) and I(L) is either 1,10-phenathroline, 4-methyl-1,10-phen...

Tetraaqua(3,4,7,8-tetramethyl-1,10-phenanthroline-kappa2N,N')zinc(II) thiosulfate.

Acta Crystallogr. C 60(Pt 9) , m451-3, (2004)

In the title complex of zinc(II) with 3,4,7,8-tetramethyl-1,10-phenanthroline (tmph), viz. [Zn(C16H16N2)(H2O)4](S2O3), the metal atom has a monomeric octahedral ZnN2O4 complex environment comprising t...

Dinuclear Cu(II) hypocrellin B complexes with enhanced photonuclease activity.

Inorg. Chem. 49(21) , 10108-16, (2010)

Five new dinuclear Cu(II) complexes were designed and synthesized, using hypocrellin B, a naturally occurring photosensitizer that has received extensive studies as promising photodynamic therapy (PDT...


More Articles

Related Compounds

  • 3,4,7,8-tetramethyl-1,10-phenanthroline 1-oxide
  • 3,4,7,8-tetramethyl-1,10-phenanthroline ferrous sulfate
  • tris(3,4,7,8-tetramethyl-1,10-phenanthroline)ruthenium(II)
  • Dibromo(3,4,7,8-tetramethyl-1,10-phenanthroline-κN1,κN10)-Nickel
  • Dichloro(3,4,7,8-tetramethyl-1,10-phenanthroline-κN1,κN10)-Nickel
  • cycloocta-1,5-diene; rhodium; 3,4,7,8-tetramethyl-1,10-phenanthroline-1,10-diide