4,4'-Bis(chloromethyl)biphenyl

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Names

[ CAS No. ]:
1667-10-3

[ Name ]:
4,4'-Bis(chloromethyl)biphenyl

[Synonym ]:
4,4′-Bis(chloromethyl)biphenyl
1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene
4,4'-Bis(chloromethyl)-1,1'-biphenyl
EINECS 216-784-4
1,1'-Biphenyl, 4,4'-bis(chloromethyl)-
4,4'-Bis(chloromethyl)biphenyl
MFCD00674019
4,4-Bis(Chloromethyl)Biphenyl

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
380.0±37.0 °C at 760 mmHg

[ Melting Point ]:
126 °C (dec.)(lit.)

[ Molecular Formula ]:
C14H12Cl2

[ Molecular Weight ]:
251.151

[ Flash Point ]:
196.3±19.8 °C

[ Exact Mass ]:
250.031601

[ LogP ]:
4.51

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.585

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Hazard Class ]:
8.0

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Formaldehyde
  • Biphenyl
  • 4,4'-Biphenyldiyldimethanol
  • Biphenyl-4,4'-dicarboxylic acid
  • BI-P-TOLYL
  • BIS(CHLOROMETHYL) ETHER
  • Carbon disulphide
  • Hydrochloric acid

DownStream

  • [4,4'-Biphenyldiylbis(methylene)]bis(phosphonic acid)
  • 4,4'-Biphenyldicarbaldehyde
  • 4,4'-Biphenyldiyldimethanol
  • 4,4'-Bis(diethoxyphosphono-methyl)-Biphenyl
  • 2,2'-(4,4'-Biphenyldiyl)diacetic acid
  • 2,2'-biphenyl-4,4'-diyldiacetonitrile
  • 4,4'-Bis[(para-formylphenoxy)methyl]biphenyl
  • 4,4'-dimethyl-d6-diphenyl
  • [4-[4-(sulfanylmethyl)phenyl]phenyl]methanethiol
  • 4,4-Divinyl-p-biphenyl

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Esterification of sodium 4-hydroxybenzoate by ultrasound-assisted solid-liquid phase-transfer catalysis using dual-site phase-transfer catalyst.

Ultrason. Sonochem. 21(1) , 395-400, (2014)

The catalytic esterification of sodium 4-hydroxybenzoate with benzyl bromide by ultrasound-assisted solid-liquid phase-transfer catalysis (U-SLPTC) was investigated using the novel dual-site phase-tra...

Pyrolytic carbon from an aromatic precursor and its application as a counter electrode in dye-sensitized solar cells.

Chemistry 17(4) , 1358-64, (2011)

Pyrolytic carbon thin films were deposited on quartz plates through a chemical vapor deposition process, by using a biphenyl precursor, 4,4'-bis(chloromethyl-1,1'-biphenyl). The pyrolytic carbons were...

Reaction of 4, 4'-bis (chloromethyl)-1, 1'-biphenyl and phenol in two-phase medium via phase-transfer catalysis. Wang M-L and Lee Z-F.

J. Mol. Catal. A: Chem. 264(1) , 119-27, (2007)


More Articles

Related Compounds

  • 4,4'-bis(chloromethyl)-1,1'-methylenebisnaphthalene
  • 4,4'-Bis(chloromethyl)-2,2'-bipyridine
  • 4,4'-bis(chloromethyl)diphenylmethane
  • 4,4'-bis(chloromethyl)diphenyl sulfide
  • bis[4-(chloromethyl)phenyl]diazene
  • 1-(chloromethyl)-4-[2-[4-(chloromethyl)phenyl]ethyl]benzene