3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-

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Names

[ CAS No. ]:
1686-14-2

[ Name ]:
3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-

[Synonym ]:
EINECS 216-869-6
α-Pinene oxide
Alpha-Pinene Oxide
2,3-Epoxypinane
Pinane, 2,3-epoxy-, (-)-
MFCD00066955

Chemical & Physical Properties

[ Density]:
1.027g/cm3

[ Boiling Point ]:
102 - 103ºC at 30 mm Hg

[ Molecular Formula ]:
C10H16O

[ Molecular Weight ]:
152.23300

[ Flash Point ]:
65.6ºC

[ Exact Mass ]:
152.12000

[ PSA ]:
12.53000

[ LogP ]:
2.20990

[ Index of Refraction ]:
n20/D 1.469(lit.)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TK4565000
CHEMICAL NAME :
Pinane, 2,3-epoxy-
CAS REGISTRY NUMBER :
1686-14-2
BEILSTEIN REFERENCE NO. :
0080362
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C10-H16-O
MOLECULAR WEIGHT :
152.26

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intramuscular
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
500 umol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
TK4565000

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Alpha-pinene
  • Octanoic acid
  • (+)-alpha-Pinene
  • α-methylstyrene

DownStream

  • α-campholenaldehyde
  • trans-Sobrerol
  • [1R-(1alpha,3beta,5alpha)]-6,6-dimethyl-2-methylenebicyclo[3.1.1]heptan-3-ol
  • (E)-carveol
  • isopinocamphone
  • laevo-pinocarveol
  • p-cymene

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Secondary organic aerosol from alpha-pinene ozonolysis in dynamic chamber system.

Indoor Air 19(4) , 335-45, (2009)

The formation of secondary organic aerosol (SOA) produced from alpha-pinene ozonolysis was examined using a dynamic chamber system that allowed the simulation of ventilated indoor environments. Partic...

Improvement of P450(BM-3) whole-cell biocatalysis by integrating heterologous cofactor regeneration combining glucose facilitator and dehydrogenase in E. coli.

Appl. Microbiol. Biotechnol. 78(1) , 55-65, (2008)

Escherichia coli BL21, expressing a quintuple mutant of P450(BM-3), oxyfunctionalizes alpha-pinene in an NADPH-dependent reaction to alpha-pinene oxide, verbenol, and myrtenol. We optimized the whole-...

Optimization of isonovalal production from alpha-pinene oxide using permeabilized cells of Pseudomonas rhodesiae CIP 107491.

Appl. Microbiol. Biotechnol. 60(5) , 534-40, (2003)

Optimization studies on the synthesis of isonovalal from alpha-pinene oxide by Pseudomonas rhodesiae CIP 107491 operated in a biphasic medium are presented. Three key parameters are identified. The fi...


More Articles

Related Compounds

  • 3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-, (1R,2S,4R,6R)-
  • (1α,2β,4β,6α)-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane
  • [1S-(1alpha,2alpha,4alpha,6alpha)]-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane
  • [1R-(1alpha,2beta,4beta,5alpha,6alpha)]-5,7,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane
  • [1R-(1alpha,2beta,4beta,6alpha)]-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane
  • (1α,2β,4β,6α)-()-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane
  • 4-Methoxy-2-methyl-6-(4-tosylpiperazin-1-yl)pyrimidine
  • 4-Methoxy-6-(4-((4-methoxyphenyl)sulfonyl)piperazin-1-yl)-2-methylpyrimidine
  • 4-Methoxy-2-methyl-6-(4-(naphthalen-2-ylsulfonyl)piperazin-1-yl)pyrimidine
  • 4-(4-((1,2-Dihydroacenaphthylen-3-yl)sulfonyl)piperazin-1-yl)-6-methoxy-2-methylpyrimidine
  • 4-Methoxy-6-(4-((4-methoxy-3-methylphenyl)sulfonyl)piperazin-1-yl)-2-methylpyrimidine
  • 4-(4-((2-Chlorophenyl)sulfonyl)piperazin-1-yl)-6-methoxy-2-methylpyrimidine
  • 4-(4-((2,3-Dihydrobenzo[b][1,4]dioxin-6-yl)sulfonyl)piperazin-1-yl)-6-methoxy-2-methylpyrimidine
  • N-(4-((4-(2-methyl-6-propoxypyrimidin-4-yl)piperazin-1-yl)sulfonyl)phenyl)acetamide
  • 4-(4-((5-Methoxy-2,4-dimethylphenyl)sulfonyl)piperazin-1-yl)-2-methyl-6-propoxypyrimidine
  • 4-(4-((2,5-Dimethoxyphenyl)sulfonyl)piperazin-1-yl)-2-methyl-6-propoxypyrimidine
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