Vanadium(V) oxytriethoxide

Names

[ CAS No. ]:
1686-22-2

[ Name ]:
Vanadium(V) oxytriethoxide

[Synonym ]:
EINECS 216-870-1
vanadium(v) oxytriethoxide
MFCD00799170

Chemical & Physical Properties

[ Density]:
1.139

[ Boiling Point ]:
72.6ºC at 760mmHg

[ Molecular Formula ]:
C₆H₁₅O₄V

[ Molecular Weight ]:
202.12200

[ Flash Point ]:
8.9ºC

[ Exact Mass ]:
202.04100

[ PSA ]:
44.76000

[ LogP ]:
1.34280

[ Index of Refraction ]:
1.508-1.512

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Vanadium(V) trichloride oxide
Diethylamine
Urea
Ethanol
Sodium ethoxide
Bromoethane
[V2(μ-2,2'-(imidazolidine-1,3-diylbis(methylene))bis(4-(1,1,3,3-tetramethylbutyl-2-yl)phenolato)-κ4O,N,N,O)(μ-OEt)2(O)2(OEt)2]

DownStream

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Stepwise Cluster Assembly Using VO(2)(acac) as a Precursor: cis-[VO(OCH(CH(3))(2))(acac)(2)], [V(2)O(2)(&mgr;-OCH(3))(2)(acac)(2)(OCH(3))(2)], [V(3)O(3){&mgr;,&mgr;-(OCH(2))(3)CCH(3)}(2)(acac)(2)(OC(2)H(5))], and [V(4)O(4)(&mgr;-O)(2)(&mgr;-OCH(3))(2)(&mgr;(3)-OCH(3))(2)(acac)(2)(OCH(3))(2)].2CH(3)CN(1).

Inorg. Chem. 37 , 5439, (1998)

The studies of an underexplored synthetic reagent, VO(2)(acac) (Hacac = acetylacetone) and semirational strategies for the formation of a complete series of simple vanadium(V) alkoxide clusters in alc...