(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl)

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Names

[ Name ]:
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N-bis(2-diphenylphosphinobenzoyl)

[Synonym ]:
Trost ligand
N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]
MFCD01631274
2-diphenylphosphanyl-N-[(1S,2S)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide
Trost's ligand
(S,S)-DACH-phenyl Trost ligand
Benzamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

Chemical & Physical Properties

[ Boiling Point ]:
817.0±65.0 °C at 760 mmHg

[ Melting Point ]:
134-136ºC

[ Molecular Formula ]:
C₄₄H₄₀N₂O₂P₂

[ Molecular Weight ]:
690.748

[ Flash Point ]:
447.9±34.3 °C

[ Exact Mass ]:
690.256531

[ PSA ]:
85.38000

[ LogP ]:
9.87

[ Vapour Pressure ]:
0.0±2.9 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S36-S37-S39

[ RIDADR ]:
NONH for all modes of transport

Articles

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

Chem. Rev. 96 , 395, (1996)

Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

Chem. Rev. 103 , 2921, (2003)

Trost, B.M. et al.

J. Am. Chem. Soc. 124 , 11616, (2004)

(1S,2S)-(-)-1,2-Dicyclopropylethylenediamine dihydrochloride
(1S,2S)-(-)-1,2-Diaminocyclohexane L-Tartrate
(1S,2S)-(+)-2-BENZYLOXYCYCLOHEXYLAMINE
N,N'-((1S,2S)-CYCLOHEXANE-1,2-DIYL)BIS(2-(DIPHENYLPHOSPHINO)-1-NAPHTHAMIDE)
(1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine
(4R)-3-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-4,4-dimethylpentanoyl}-1,3-thiazolidine-4-carboxylic acid
3-[2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-3,3-dimethylbutanamido]cyclohexane-1-carboxylic acid
4-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-4-[(3-methoxy-2-methyl-3-oxopropyl)(methyl)carbamoyl]butanoic acid
4-({2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]butanamido}methyl)benzoic acid
1-[2-cyclopropyl-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)propanoyl]-3-methoxypyrrolidine-3-carboxylic acid
1-{1-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclobutanecarbonyl}-3-methoxypyrrolidine-3-carboxylic acid
2-(1-{5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,2-oxazol-3-yl}-N-(prop-2-yn-1-yl)formamido)acetic acid
3-[2-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,2-oxazol-3-yl}formamido)ethoxy]propanoic acid
2-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,2-oxazol-3-yl}formamido)-3-methoxy-2-methylpropanoic acid
2-(1-{5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-1,2-oxazol-3-yl}-N-(2-hydroxyethyl)formamido)acetic acid

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