1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE

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Names

[ CAS No. ]:
17082-61-0

[ Name ]:
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE

[Synonym ]:
MFCD00010798
[1-Cyclobutene-1,2-diylbis(oxy)]bis(trimethylsilane)
trimethyl-(2-trimethylsilyloxycyclobuten-1-yl)oxysilane
[Cyclobut-1-ene-1,2-diylbis(oxy)]bis(trimethylsilane)
1,2-Bis(triMethylsilyloxy)cyclobutene
1,2-Bis((trimethylsilyl)oxy)cyclobut-1-ene
Cyclobutene, 1,2-bis[(trimethylsilyl)oxy]-

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
215.1±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C10H22O2Si2

[ Molecular Weight ]:
230.452

[ Flash Point ]:
61.1±0.0 °C

[ Exact Mass ]:
230.115829

[ PSA ]:
18.46000

[ LogP ]:
4.45

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.442

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38:Irritating to eyes, respiratory system and skin .

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • Diethyl succinate
  • Dimethyl succinate

DownStream

  • 4-acetyl-7a-methyl-3,5,6,7-tetrahydro-2H-inden-1-one
  • Butanoic acid,4,4-dimethoxy-,methyl ester
  • trimethyl(3-trimethylsilyloxybuta-1,3-dien-2-yloxy)silane
  • 2-Ethyl-1,3-cyclopentanedione
  • 1-(2-Hydroxy-5-methoxyphenyl)ethanone
  • 2-(β-carboxyethyl)-3-methyl-5-methoxybenzo[b]furan
  • cis-1-oxo-3a-hydroxy-7-methoxy-8b-methyl-2,3,3a,8b-tetrahydro-1H-cyclopenta[b]benzo[b]furan
  • 2-methyl-2-(2-acetoxy-5-methoxyphenyl)cyclopentane-1,3-dione
  • 2-Methylcyclopentane-1,3-dione
  • ethyl 4-cyclohexyl-4-oxobutanoate

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

J. Am. Chem. Soc. 106 , 1759, (1984)

Organic Synth. 7 , 112, (1990)

Photoaddition with 1, 2-bis (trimethylsiloxy) cyclobutene: a versatile entry to the stereocontrolled total synthesis of various sesquiterpenes and diterpenes. de Keukeleire D, et al.

J. Photochem. 28(2) , 165-74, (1985)


More Articles

Related Compounds

  • 1,2-bis(trimethylsilyloxy)octane
  • 1,2-Bis(trimethylsilyloxy)cyclohexene
  • 1,2-Bis(trimethylsilyloxy)benzene
  • 1,2-bis(trimethylsilyloxy)-3,3,6,6-tetramethylcyclohex-1-ene
  • trans-1,2-Bis-trimethylsilyloxy-ethylen
  • Acenaphthylene, 1,2-bis(trimethylsilyloxy)-
  • 3-(3-Bromophenyl)-1,4,6,7-tetrahydropyrano[4,3-c]pyrazole
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 3-Pyridinecarboxylic acid, 5-acetyl-2-methoxy-, methyl ester
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine