carbon monoxide; rhodium; triphenylphosphane

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Names

[ CAS No. ]:
17185-29-4

[ Name ]:
carbon monoxide; rhodium; triphenylphosphane

[Synonym ]:
Carbonyltris(triphenylphosphine)rhodiuM(I)
(PPh3)3Rh(CO)H
Carbonylhydrotris(triphenylphosphin)rhodium
MFCD00151644
Carbonyltris(triphenylphosphine)rhodium(I) Hydride
EINECS 241-230-3
[(PPh3)3Rh(H)(CO)]
Carbonyltris(triphenylphosphine)rhodium(I)hydride
Tris(triphenylphosphine)rhodium carbonyl hydride
(betab-5-23)-rhodiu
RhH(CO)(triphenylphosphine)3
Carbonyl triphenylphosphine rhodiuM hydride
Carbonyltris(triphen
Hydridocarbonyltris(triphenylphosphine)rhodium
Tris(triphenylphosphine)carbonylrhodium hydride
Carbonyltris(triphenylphosphine)rhodium
Tris(triphenylphosphine)rhodium(I) Carbonyl Hydride
carbonylhydrotris(triphenylphosphine)rhodium
(PPh3)3(CO)HRh
Rh(PPh3)3(CO)H
Hydridocarbonyltris(triphenylphosphine)rhodium(I)
Carbonylhydridotris(triphenylphosphine)rhodium(I)
[HRh(CO)(PPh3)3]

Chemical & Physical Properties

[ Boiling Point ]:
360ºC at 760mmHg

[ Melting Point ]:
150 °C (dec.)(lit.)

[ Molecular Formula ]:
C55H45OP3Rh

[ Molecular Weight ]:
917.772

[ Flash Point ]:
181.7ºC

[ Exact Mass ]:
917.173828

[ PSA ]:
40.77000

[ LogP ]:
10.12640

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R23/24/25

[ Safety Phrases ]:
S36/37/39-S45-S36/37

[ RIDADR ]:
UN 2811 6.1/PG 2

[ WGK Germany ]:
1

[ Packaging Group ]:
III

[ Hazard Class ]:
4.3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Wilkinson's catalyst
  • Formaldehyde
  • trans-[(carbonyl)(carboxylato)(triphenylphosphine)2rhodium(I)]
  • Triphenylphosphine
  • [(CO)2Rh(μ-,kappa.O,O'-HCO2)]2
  • Hydridotetrakis(triphenylphosphine)rhodium(I)
  • sodiumborohydride
  • trans-Carbonylchlorobis-(triphenylphosphino)-rhodium
  • Hydrazine hydrate

DownStream

Related Compounds

  • carbon monoxide; rhodium(+1) cation; dichloride
  • Rhodium (triphenylphosphine)carbonylacetylacetonate
  • Carbon monooxide-rhodium (8:3)
  • Carbon monooxide-rhodium (3:1)
  • carbon monoxide; ruthenium; triphenylphosphane
  • carbon monoxide,phthalic acid,rhodium
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 4,5,6,7-tetrahydro-1,3-benzothiazole-2-carboxylate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 2-acetamido-4-methylpent-4-enoate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 2-methoxy-6-methylbenzoate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 1-benzothiophene-7-carboxylate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 3-({[(9H-fluoren-9-yl)methoxy]carbonyl}(2-methylpropyl)amino)propanoate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 3-{[(benzyloxy)carbonyl]amino}-3-methylbutanoate
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 3-benzyl-3-azabicyclo[3.1.1]heptane-6-carboxylate
  • 1,1,1-Trifluoro-3-(2-fluoropyridin-3-yl)propan-2-one
  • Tert-butyl 2-{[4-(4-bromophenyl)azocan-4-yl]oxy}acetate
  • [1-(2,3-Dihydro-1,4-benzodioxin-5-yl)-2-methylpropan-2-yl](methyl)amine
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