4,4′-dimethoxy-2,2′-bipyridine

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Names

[ CAS No. ]:
17217-57-1

[ Name ]:
4,4′-dimethoxy-2,2′-bipyridine

[Synonym ]:
4,4'-DIMETHOXY-2,2'-BIPYRIDINE
4,4'-DiMethoxy-2,2'-bipyridyl
MFCD00233880
4,4'-Dimethoxy-[2,2']bipyridinyl
4,4′-dimethoxy-2,2′-bipyridine
4-methoxy-2-(4-methoxypyridin-2-yl)pyridine
2,2'-Bipyridine, 4,4'-dimethoxy-

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
347.6±37.0 °C at 760 mmHg

[ Melting Point ]:
168-171ºC(lit.)

[ Molecular Formula ]:
C12H12N2O2

[ Molecular Weight ]:
216.236

[ Flash Point ]:
127.0±16.8 °C

[ Exact Mass ]:
216.089874

[ PSA ]:
44.24000

[ LogP ]:
1.53

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.551

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Methoxypyridine
  • 4,4'-dimethyloxy-2,2'-bipyridine 1,1'-dioxide
  • 2-Chloro-4-methoxypyridine
  • 4,4'-DINITRO-[2,2'-BIPYRIDINE] 1,1'-DIOXIDE
  • 2,2'-Bipyridine
  • 2,2'-Bipyridyl 1,1'-Dioxide

DownStream

  • 2,2'-bipyridyl-4,4'-diphosphonic ethyl ester
  • 4,4′-dibromo-2,2′-bipyridine
  • 2,2'-Bipyridine-4,4'-diol

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis and characterization of a new family of luminescent cis-(4, 4'-X2-5, 5'-Y2-2, 2'-bipyridine) 2Os (CO) Cl (PF6) complexes (X= NEt2, OMe, Me, H, Cl, Y= H; X= H, Y= Me; X= Y= Me): control of excited-state properties by bipyridyl substituents. Della CL, et al.

Inorg. Chem. 29(15) , 2792-2798, (1990)

Efficient osmium sensitizers containing 2,2'-bipyridine-4,4'-bisphosphonic acid ligand. Zabri H, et al.

J. Photochem. Photobiol. A: Chem. 166(1) , 99-106, (2004)

Photochemical isomerization of trans- to cis-[RuCl2(dppb)(4,4'-X2-2,2'-bipy)](X=-H,-NO2,-Me,-COOH,-SMe,-O=SMe,-Cl,-OMe) complexes. Santiago MO, et al.

Polyhedron 22(24) , 3205-3211, (2003)


More Articles

Related Compounds

  • 4,4′-dibromo-2,2′-bipyridine
  • 4,4′-dinonyl-2,2′-bipyridine
  • 4-4-DIMETHOXY-2-2-BIPYRIDINE
  • (SP-4-2)-[4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-κN1,κN1′]dibromo-Nickel
  • 5,5'-bis(bromomethyl)-2,2'-bipyridine
  • [Ir(dtbbpy)(ppy)2][PF6]
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • N-[2-(2-Pyridinyldithio)ethyl]-2-propenamide
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (1-((1-Methylazetidin-3-yl)methyl)piperidin-2-yl)methanamine
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine