Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

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Names

[ CAS No. ]:
172222-30-9

[ Name ]:
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

[Synonym ]:
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
MFCD01090946
GRUBBS CATALYST
Grubbs catalyst,1st Generation
ruthenium phosphine
Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride
Bis(tricyclohexylphosphine)benzylidene ruthenium (IV) dichloride

Chemical & Physical Properties

[ Boiling Point ]:
383.4ºC at 760 mmHg

[ Melting Point ]:
153ºC (dec.)

[ Molecular Formula ]:
C44H38Cl2P2Ru

[ Molecular Weight ]:
800.696

[ Flash Point ]:
195.6ºC

[ Exact Mass ]:
800.086975

[ PSA ]:
27.18000

[ LogP ]:
10.59820

[ Vapour Pressure ]:
9.7E-06mmHg at 25°C

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1325

[ WGK Germany ]:
3

[ Packaging Group ]:
Ⅱ

[ HS Code ]:
28439000

Precursor & DownStream

Precursor

DownStream

  • Umicore M2
  • TRICYCLOHEXYLPHOSPHINE [1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE] [3-PHENYL-1H-INDEN-1-YLIDENE] RUTHENIUM (II) DICHLORIDE
  • DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)

Articles

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture).

Angew. Chem. Int. Ed. Engl. 45 , 3760, (2006)

Effects of Olefin Substitution on the Ring-Closing Metathesis of Dienes.

J. Org. Chem. 62 , 7310, (1997)

Ruthenium alkylidene 1 and molybdenum alkylidene 2 have been utilized in the ring-closing metathesis (RCM) of dienes containing gem-disubstituted olefins to yield tri- and tetrasubstituted cyclic olef...


More Articles

Related Compounds

  • 1-(4-(Trifluoromethoxy)phenyl)pyrrolidin-3-amine
  • 3-amino-N-[2-(difluoromethoxy)phenyl]-2-methylbenzamide
  • 4-Amino-2-chloro-N-(2-(difluoromethoxy)phenyl)benzamide
  • 2-(4-Isopropylthiophen-2-YL)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
  • N-(5-ethyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-2-(2-methoxyphenoxy)acetamide
  • N-(5-allyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-3-methylbutanamide
  • N-(5-allyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-2-methylbenzamide
  • N-(5-allyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-3-(2-chlorophenyl)-5-methylisoxazole-4-carboxamide
  • N-(5-allyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)pivalamide
  • N-(5-allyl-3,3-dimethyl-4-oxo-2,3,4,5-tetrahydrobenzo[b][1,4]oxazepin-8-yl)-2-oxo-2H-chromene-3-carboxamide
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