Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

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Names

[ CAS No. ]:
172222-30-9

[ Name ]:
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium

[Synonym ]:
Benzylidenebis(tricyclohexylphosphine)dichlororuthenium
MFCD01090946
GRUBBS CATALYST
Grubbs catalyst,1st Generation
ruthenium phosphine
Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride
Bis(tricyclohexylphosphine)benzylidene ruthenium (IV) dichloride

Chemical & Physical Properties

[ Boiling Point ]:
383.4ºC at 760 mmHg

[ Melting Point ]:
153ºC (dec.)

[ Molecular Formula ]:
C44H38Cl2P2Ru

[ Molecular Weight ]:
800.696

[ Flash Point ]:
195.6ºC

[ Exact Mass ]:
800.086975

[ PSA ]:
27.18000

[ LogP ]:
10.59820

[ Vapour Pressure ]:
9.7E-06mmHg at 25°C

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
1325

[ WGK Germany ]:
3

[ Packaging Group ]:
Ⅱ

[ HS Code ]:
28439000

Precursor & DownStream

Precursor

DownStream

  • Umicore M2
  • TRICYCLOHEXYLPHOSPHINE [1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE] [3-PHENYL-1H-INDEN-1-YLIDENE] RUTHENIUM (II) DICHLORIDE
  • DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)

Articles

Ruthenium-based heterocyclic carbene-coordinated olefin metathesis catalysts.

Chem. Rev. 110 , 1746, (2010)

Olefin-metathesis catalysts for the preparation of molecules and materials (Nobel Lecture).

Angew. Chem. Int. Ed. Engl. 45 , 3760, (2006)

Effects of Olefin Substitution on the Ring-Closing Metathesis of Dienes.

J. Org. Chem. 62 , 7310, (1997)

Ruthenium alkylidene 1 and molybdenum alkylidene 2 have been utilized in the ring-closing metathesis (RCM) of dienes containing gem-disubstituted olefins to yield tri- and tetrasubstituted cyclic olef...


More Articles

Related Compounds

  • Ethyl 2-{1-[(methylamino)methyl]cyclohexyl}acetate
  • (2R)-2-{[(tert-butoxy)carbonyl]amino}-3-(3-methyl-3H-diazirin-3-yl)propanoic acid
  • Tert-butyl 4,4-dimethyl-2-[(methylamino)methyl]pyrrolidine-1-carboxylate
  • tert-butyl N-(1-{6-[(methylamino)methyl]pyridin-2-yl}pyrrolidin-3-yl)carbamate
  • 4-(Aminomethyl)benzene-1-carbothioamide hydrochloride
  • tert-butyl N-{1-amino-3-[3-(propan-2-yl)phenyl]propan-2-yl}carbamate
  • 4-(4-chlorophenyl)-5-(difluoromethyl)-1-methyl-1H-pyrazole
  • 1-(2-Propoxyethyl)cyclopropane-1-sulfonyl chloride
  • 2,4,6-trimethyl-3-(1H-pyrazol-4-yl)aniline
  • 4-(3-Amino-2,4,6-trimethylphenyl)thiophene-2-carbaldehyde
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