trans-di-(my-Acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium (II)

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Names

[ CAS No. ]:
172418-32-5

[ Name ]:
trans-di-(my-Acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium (II)

[Synonym ]:
TRANS-DI(μ-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)
MFCD01075746
TRANS-DI(MU-ACETATO)BIS[O-(DI-O-TOLYLPHOSPHINO)BENZYL]DIPALLADIUM (II)
trans-Di-mu-acetatobis[2-(di-o-tolylphosphino)benzyl]dipalladium(II)

Chemical & Physical Properties

[ Melting Point ]:
230ºC

[ Molecular Formula ]:
C46H46O4P2Pd2

[ Molecular Weight ]:
937.643

[ Exact Mass ]:
936.094116

[ PSA ]:
79.78000

[ LogP ]:
8.78220

[ Appearance of Characters ]:
crystal | yellow

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
28439000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Palladium diacetate
  • Tri-o-tolylphosphine

DownStream

  • BIS(TRI-O-TOLYLPHOSPHINE)PALLADIUM(0)

Articles

Palladium-catalyzed dehydrohalogenative polycondensation of 2-bromo-3-hexylthiophene: an efficient approach to head-to-tail poly(3-hexylthiophene).

J. Am. Chem. Soc. 132 , 11420, (2010)

Dehydrohalogenative polycondensation of 2-bromo-3-hexylthiophene was successful with Herrmann's catalyst and tris(2-dimethylaminophenyl)phosphine as catalyst precursors, giving head-to-tail poly(3-hex...

Herrmann-Beller phosphapalladacycle-catalyzed addition of alkynes to norbornadienes.

Org. Lett. 8 , 4315, (2006)

Herrmann-Beller (H-B) phosphapalladacycle selectively catalyzed the addition of terminal alkynes across one double bond of norbornadiene to afford exo-5-alkynyl-bicyclo[2.2.1]hept-2-enes. The reaction...

trans-Di (µ-acetato)-bis [o-(di-o-tolylphosphino) benzyl] dipalladium (II). Speicher A, et al.

J. Prakt. Chem. 341(6) , 605-8, (1999)


More Articles

Related Compounds

  • 1'-(Cyclohex-3-ene-1-carbonyl)-4-methoxy-1,4'-bipiperidine
  • 3-(3-Chlorophenyl)-1-{4-methoxy-[1,4'-bipiperidine]-1'-yl}propan-1-one
  • 3-(2,6-Dichlorophenyl)-1-(4-methoxy-[1,4'-bipiperidin]-1'-yl)propan-1-one
  • 3-(2-Fluorophenyl)-1-{4-methoxy-[1,4'-bipiperidine]-1'-yl}propan-1-one
  • 1-{4-Methoxy-[1,4'-bipiperidine]-1'-yl}-3-[4-(methylsulfanyl)phenyl]propan-1-one
  • 1-{4-Methoxy-[1,4'-bipiperidine]-1'-yl}-3-[4-(trifluoromethyl)phenyl]propan-1-one
  • 3-(3-Chloro-4-fluorophenyl)-1-{4-methoxy-[1,4'-bipiperidine]-1'-yl}propan-1-one
  • 1'-(2-Ethyl-1,3-benzothiazole-6-carbonyl)-4-methoxy-1,4'-bipiperidine
  • 1-{4-Methoxy-[1,4'-bipiperidine]-1'-yl}-2,2-diphenylethan-1-one
  • 1-{4-methoxy-[1,4'-bipiperidine]-1'-yl}-2-(1H-pyrazol-1-yl)ethan-1-one
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