Methyl 2,3-dibromopropionate

Names

[ CAS No. ]:
1729-67-5

[ Name ]:
Methyl 2,3-dibromopropionate

[Synonym ]:
MFCD00017882
EINECS 217-044-3
methyl 2,3-dibromopropanoate
Methyl 2,3-Dibromopropionate

Chemical & Physical Properties

[ Density]:
1.944 g/mL at 20 °C(lit.)

[ Boiling Point ]:
83-86 °C10 mm Hg(lit.)

[ Melting Point ]:
8ºC

[ Molecular Formula ]:
C₄H₆Br₂O₂

[ Molecular Weight ]:
245.89700

[ Flash Point ]:
-33 °C

[ Exact Mass ]:
243.87300

[ PSA ]:
26.30000

[ LogP ]:
1.31780

[ Vapour Pressure ]:
0.243mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.514

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37

[ Safety Phrases ]:
S26-S36-S16

[ RIDADR ]:
UN 2398 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2915900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Dimethyl 1H-pyrazole-3,5-dicarboxylate
3,5-Pyrazoledicarboxylic acid monohydrate
Methyl 2-bromoacrylate
2,3-Dihydro-benzo[1,4]dioxine-2-carboxylic acid methyl ester
3-Carboxylato-2,3-dihydro-8-hydroxythiazolo[3,2-a]pyridinium
trimethyl cyclopropane-1,1,2-tricarboxylate
methyl 3-(benzenesulfonyl)prop-2-enoate
2-Aziridinecarboxylicacid, 1-(1,1-dimethylethyl)-, methyl ester
methyl 2-bromo-3-methoxypropanoate
2-Carbomethoxyaziridine

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

2H-Azirines as dipolarophiles. Pinho e Melo TMVD, et al.

Tetrahedron Lett. 44(33) , 6313-15, (2003)

Regiospecific and Enantiospecific Ring Opening of Methyl (+)-(1'R, 2R)-and (-)-(1'R, 2S)-1-(2-phenylethanol) Aziridine-2-carboxylates. Gnecco D, et al.

Molecules 5(8) , 998-1003, (2000)

Synthesis of substituted 3, 4-dihydro-2< i> H</i>-pyrido [3, 2-< i> b</i>][1, 4] oxazine as new scaffolds for potential bioactive compounds. Henry N, et al.

Tetrahedron 62(10) , 2405-12, (2006)

methyl 2-[(3,4-dichlorophenyl)carbamoylamino]-2-methyl-propanoate
Methyl 2,3,4-Tri-O-acetyl-6-deoxy-β-D-galactopyranoside
methyl 2-[(3-benzylsulfanyl-2-phenylmethoxycarbonylamino-propanoyl)amino]acetate
methyl 2-[[3-(4-hydroxyphenyl)-2-(tert-butoxycarbonylamino)propanoyl]amino]acetate
methyl-(2,3,3-trichloro-1-trichloromethyl-propyl)-ether
methyl 2,3-dibenzhydrylidenecyclopropane-1-carboxylate