Benzyl 2-(1H-benzo[d][1,2,3]triazol-1-yl)-2-oxoethylcarbamate
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Names
[ CAS No. ]:
173459-80-8
[ Name ]:
Benzyl 2-(1H-benzo[d][1,2,3]triazol-1-yl)-2-oxoethylcarbamate
[Synonym ]:
Z-GLY-BT
(2-benzotriazol-1-yl-2-oxoethyl)carbamic acid benzyl ester
Cbz-Gly-Bt
Cbz-Gly
Chemical & Physical Properties
[ Molecular Formula ]:
C16H14N4O3
[ Molecular Weight ]:
310.30700
[ Exact Mass ]:
310.10700
[ PSA ]:
86.11000
[ LogP ]:
2.38880
Safety Information
[ Symbol ]:
GHS07
[ Signal Word ]:
Warning
[ Hazard Statements ]:
H315-H319-H335
[ Precautionary Statements ]:
P261-P305 + P351 + P338
[ RIDADR ]:
NONH for all modes of transport
Articles
J. Org. Chem. 76 , 4884-4893, (2011)
Reactions of O-Pg(α-hydroxyacyl)benzotriazoles with (a) unprotected α-hydroxycarboxylic acids, (b) amino acids, and (c) amines afforded, respectively, chirally pure (a) oligoesters, (b) depsidipeptide...
J. Org. Chem. 74th ed.,, 8690-8694, (2009)
N-(Pg-alpha-aminoxy acids) 1a-g are converted to N-(Pg-alpha-aminoxyacyl)benzotriazoles 2a-g, which react under mild conditions with amines, alpha-amino acids/alpha-dipeptides, and alpha-aminoxy acids...
Abdelmajeid, A.; Tala, S. R.; Amine, M. S.; Katritzky, A. R.Synthesis , 2995-3005, (2011)