Benzyl 2-(1H-benzo[d][1,2,3]triazol-1-yl)-2-oxoethylcarbamate

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Names

[ CAS No. ]:
173459-80-8

[ Name ]:
Benzyl 2-(1H-benzo[d][1,2,3]triazol-1-yl)-2-oxoethylcarbamate

[Synonym ]:
Z-GLY-BT
(2-benzotriazol-1-yl-2-oxoethyl)carbamic acid benzyl ester
Cbz-Gly-Bt
Cbz-Gly

Chemical & Physical Properties

[ Molecular Formula ]:
C₁₆H₁₄N₄O₃

[ Molecular Weight ]:
310.30700

[ Exact Mass ]:
310.10700

[ PSA ]:
86.11000

[ LogP ]:
2.38880

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ RIDADR ]:
NONH for all modes of transport

Articles

Benzotriazole-mediated syntheses of depsipeptides and oligoesters.

J. Org. Chem. 76 , 4884-4893, (2011)

Reactions of O-Pg(α-hydroxyacyl)benzotriazoles with (a) unprotected α-hydroxycarboxylic acids, (b) amino acids, and (c) amines afforded, respectively, chirally pure (a) oligoesters, (b) depsidipeptide...

Efficient preparation of aminoxyacyl amides, aminoxy hybrid peptides, and alpha-aminoxy peptides.

J. Org. Chem. 74th ed.,, 8690-8694, (2009)

N-(Pg-alpha-aminoxy acids) 1a-g are converted to N-(Pg-alpha-aminoxyacyl)benzotriazoles 2a-g, which react under mild conditions with amines, alpha-amino acids/alpha-dipeptides, and alpha-aminoxy acids...

Abdelmajeid, A.; Tala, S. R.; Amine, M. S.; Katritzky, A. R.

Synthesis , 2995-3005, (2011)