H-Gly-Gly-OBzl · p-tosylate

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Names

[ Name ]:
H-Gly-Gly-OBzl · p-tosylate

[Synonym ]:
Gly-Gly benzyl ester p-toluenesulfonate salt
H-Gly-Gly-OBzl·Tos-OH
Benzyl glycylglycinate 4-methylbenzenesulfonate (1:1)
Glycine, glycyl-, phenylmethyl ester, 4-methylbenzenesulfonate (1:1)
Glycylglycine Benzyl Ester p-Toluenesulfonate
benzyl 2-[(2-aminoacetyl)amino]acetate,4-methylbenzenesulfonic acid
MFCD00050678
Benzyl 2-(2-aminoacetamido)acetate 4-methylbenzenesulfonate

Chemical & Physical Properties

[ Boiling Point ]:
408ºC at 760 mmHg

[ Melting Point ]:
157-159ºC

[ Molecular Formula ]:
C₁₈H₂₂N₂O₆S

[ Molecular Weight ]:
394.442

[ Flash Point ]:
200.5ºC

[ Exact Mass ]:
394.119843

[ PSA ]:
144.17000

[ LogP ]:
3.21840

[ Vapour Pressure ]:
7.26E-07mmHg at 25°C

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

H-Gly-Gly-OH
p-Toluenesulfonic acid
Benzyl alcohol

DownStream

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis of 7-substituted benzolactam-V8s and their selectivity for protein kinase C isozymes.

Org. Lett. 4 , 2377-2380, (2002)

[reaction: see text] Condensation of L-valine benzyl ester toluenesulfonic acid salt with a substituted cyclohexadione followed by aromatization with the assistance of NBS provides an N-aryl L-valine ...

A racemization test in peptide synthesis using 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride (DMT-MM).

Chem. Pharm. Bull. 50 , 549-550, (2002)

Racemization of the C-terminal amino acid (Ala) has been studied in various solvents during coupling between 4-methoxybenzyloxycarbonyl (Z(OMe))-Gly-L-Ala-OH and phenylalanine benzyl ester (H-Phe-OBzl...

H-Gly-Pro-pNA · p-tosylate
H-Gly-Obzl p-Tosylate
H-Sar-OBzl.TosOH
H-Gly-Gly-pNA · HCl
H-Gly-Gly-βNA · HBr
H-Gly-Gly-OEt · HCl
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tert-Butyl (R)-6-(2-amino-3-methoxy-3-oxopropyl)-1H-benzo[d]imidazole-1-carboxylate
(S)-2-Amino-3-(1-(tert-butoxycarbonyl)-1H-pyrrolo[2,3-b]pyridin-5-yl)propanoic acid
(S)-2-((2S,4R)-4-Hydroxypyrrolidine-2-carboxamido)butanoic acid
tert-Butyl (S)-6-(1-aminoethyl)-3,4-dihydro-1,5-naphthyridine-1(2H)-carboxylate