2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL

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Names

[ CAS No. ]:
173831-50-0

[ Name ]:
2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL

[Synonym ]:
(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthyl
(S)-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene
(R)-2,2'-Bis(methoxymethoxy)-1,1'-binaphthalene
2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
(R)-(+)-2,2′-Bis(methoxymethoxy)-1,1′-binaphthyl
MFCD03788935
1,1'-Binaphthalene, 2,2'-bis(methoxymethoxy)-

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
477.8±45.0 °C at 760 mmHg

[ Melting Point ]:
92-96ºC(lit.)

[ Molecular Formula ]:
C24H22O4

[ Molecular Weight ]:
374.429

[ Flash Point ]:
126.2±35.6 °C

[ Exact Mass ]:
374.151794

[ PSA ]:
36.92000

[ LogP ]:
4.57

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.630

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H318-H410

[ Precautionary Statements ]:
P273-P280-P305 + P351 + P338-P501

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi,N

[ Risk Phrases ]:
R41

[ Safety Phrases ]:
26-39-60-61-36/39-25

[ RIDADR ]:
UN 3077 9/PG 3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chloromethyl methyl ether
  • BINOL
  • methoxymethoxy chloride
  • (S)-(-)-1,1'-Bi-2-naphthol
  • 2-Naphthol

DownStream

  • BINOL

Articles

Cox, P. J. et al

Tetrahedron Lett. 33 , 2253, (1992)


More Articles

Related Compounds

  • 2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • (r)-(+)-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
  • (R)-3-formyl-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
  • 6,6'-dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
  • (s)-3,3'-dibromo-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl
  • (R)-6,6'-DIBROMO-2,2'-BIS(METHOXYMETHOXY)-1,1'-BINAPHTHYL
  • 4-[4-(5-Fluoropyrimidin-4-yl)piperazin-1-yl]-5-methyl-2-(methylsulfanyl)pyrimidine
  • 4-[4-(5-Chloropyrimidin-2-yl)piperazin-1-yl]-5-fluoro-2,6-dimethylpyrimidine
  • 2-Cyclopropyl-4-(difluoromethyl)-6-[4-(1,3,4-thiadiazol-2-yl)piperazin-1-yl]pyrimidine
  • 2-[4-(2-Cyclopropyl-5-fluoro-6-methylpyrimidin-4-yl)piperazin-1-yl]pyridine-3-carbonitrile
  • 7-{5-Methylpyrazolo[1,5-a]pyrimidin-7-yl}-1,3,7-triazaspiro[4.4]nonane-2,4-dione
  • 6-[4-(5-Fluoro-2,6-dimethylpyrimidin-4-yl)piperazin-1-yl]pyridine-3-carbonitrile
  • 4-{[4-(6-Ethyl-5-fluoropyrimidin-4-yl)-1,4-diazepan-1-yl]methyl}-1-methyl-1,2-dihydropyridin-2-one
  • 3,3-dimethyl-1-[5-(9-methyl-9H-purin-6-yl)-octahydropyrrolo[3,4-c]pyrrol-2-yl]butan-1-one
  • 5-Methyl-4-[4-(5-methylpyrimidin-2-yl)piperazin-1-yl]-2-(methylsulfanyl)pyrimidine
  • 2-tert-butyl-N-[(oxolan-2-yl)methyl]imidazo[1,2-b]pyridazine-6-carboxamide
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