dehydroabietic acid

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Names

[ CAS No. ]:
1740-19-8

[ Name ]:
dehydroabietic acid

[Synonym ]:
dehydroabietic acid
abietic acid, dehydro-
1,2,3,4,4a,9,10,10a-Octahydro-1,4a-dimethyl-7-(1-methylethyl)-1-phenanthrenecarboxylic acid
(+)-Dehydroabietic acid
1-Phenanthrenecarboxylic acid, 1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aS,10aR)-
Abieta-8(14),9(11),12-trien-18-oic acid
Abieta-8,11,13-trien-18-oic acid,Dehydroabietate
EINECS 217-102-8

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
425.1±34.0 °C at 760 mmHg

[ Melting Point ]:
174-176ºC

[ Molecular Formula ]:
C20H28O2

[ Molecular Weight ]:
300.435

[ Flash Point ]:
202.5±20.3 °C

[ Exact Mass ]:
300.208923

[ PSA ]:
37.30000

[ LogP ]:
6.35

[ Appearance of Characters ]:
NA

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.540

[ Storage condition ]:
?20°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TP8710000
CHEMICAL NAME :
Podocarpa-8,11,13-trien-15-oic acid, 13-isopropyl-
CAS REGISTRY NUMBER :
1740-19-8
BEILSTEIN REFERENCE NO. :
2059290
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C20-H28-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1710 mg/kg
TOXIC EFFECTS :
Autonomic Nervous System - other (direct) parasympathomimetic Behavioral - ataxia
REFERENCE :
BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 18,42,1977 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8400 mg/kg/28D-C
TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.) Biochemical - Metabolism (Intermediary) - Plasma proteins not involving coagulation
REFERENCE :
BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 18,42,1977 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2653 No. of Facilities: 1630 (estimated) No. of Industries: 16 No. of Occupations: 20 No. of Employees: 13811 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2653 No. of Facilities: 394 (estimated) No. of Industries: 8 No. of Occupations: 12 No. of Employees: 14625 (estimated) No. of Female Employees: 4688 (estimated)

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H410

[ Precautionary Statements ]:
P273-P301 + P310-P501

[ Hazard Codes ]:
T,N

[ Risk Phrases ]:
25-50

[ Safety Phrases ]:
45-61

[ RIDADR ]:
UN 2811 6.1 / PGIII

Precursor & DownStream

Precursor

  • Methyl dehydroabietate
  • abietic acid
  • acetic acid geranyl ester
  • (2E,6E)-3,7-Dimethyl-8-oxoocta-2,6-dien-1-yl acetate
  • 3-Bromocumene
  • (3-ISOPROPYLPHENYL)METHANOL
  • (E,E)-8-acetoxy-2,6-dimethyl-2,6-octadien-1-ol
  • 1-Phenanthrenecarboxylicacid, 1,2,3,4,4a,4b,5,6,10,10a-decahydro-1,4a-dimethyl-7-(1-methylethyl)-,methyl ester, (1R,4aR,4bR,10aR)-
  • Sulfuric acid
  • Ecabet

DownStream

  • Retene
  • Ecabet
  • 1-Phenanthrenecarbonitrile,1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)-, (1R,4aS,10aR)-
  • Methyl dehydroabietate
  • (+)-Dehydroabiethylamine
  • 12,14-Dichlorodehydroabietic acid
  • 1-Phenanthrenemethanol, 1,2,3,4,4a,9,10,10a-octahydro-1,4a-dimethyl-7-(1-methylethyl)-a-phenyl-

Articles

Development of ultrasonic-assisted closed in-syringe extraction and derivatization for the determination of labile abietic acid and dehydroabietic acid in cosmetics.

J. Chromatogr. A. 1371 , 20-9, (2014)

Two resin acids, abietic acid (AA) and dehydroabietic acid (DHAA), in cosmetics may cause allergy or toxicoderma, but remain inaccurately investigated due to their lability. In this work, an accurate,...

Disproportionated rosin dehydroabietic acid in neoprene surgical gloves.

Dermatitis 21(3) , 157-9, (2010)

Allergic contact dermatitis (ACD) is a well-recognized immune-mediated disease often associated with the use of vulcanization accelerator-containing latex and nitrile gloves. Potential contact allerge...

Synthesis and antibacterial evaluation of New N-acylhydrazone derivatives from dehydroabietic acid.

Molecules 17(4) , 4634-50, (2012)

A series of new N-acylhydrazone derivatives were synthesized in good yields through the reactions of dehydroabietic acid hydrazide with a variety of substituted arylaldehydes. The structures of the sy...


More Articles


Related Compounds

  • dehydroabietic acid
  • dehydroabietic acid
  • dehydroabietic acid
  • (+)-Dehydroabietic acid
  • epi-dehydroabietic acid
  • 7-Oxodehydroabietic acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • Methyl 2-(methylamino)-4,5,6,7-tetrahydro-1-benzothiophene-3-carboxylate
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 3-(4-chloro-3-methyl-1H-pyrazol-1-yl)-2-[(propan-2-yl)amino]propanoic acid
  • Methyl 5-(1-cyano-1-methylethyl)nicotinate
  • 4,6-Dichloro-2-(oxolan-2-yl)pyrimidine
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide