(Allyloxy)benzene

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Names

[ CAS No. ]:
1746-13-0

[ Name ]:
(Allyloxy)benzene

[Synonym ]:
Allyl phenyl ether
(Allyloxy)benzene
MFCD00008644
prop-2-enoxybenzene
EINECS 217-125-3

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
192.4±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C9H10O

[ Molecular Weight ]:
134.175

[ Flash Point ]:
62.8±0.0 °C

[ Exact Mass ]:
134.073166

[ PSA ]:
9.23000

[ LogP ]:
2.94

[ Vapour Pressure ]:
0.7±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.504

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DA8575000
CHEMICAL NAME :
Benzene, (2-propenyloxy)-
CAS REGISTRY NUMBER :
1746-13-0
BEILSTEIN REFERENCE NO. :
1905622
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C9-H10-O
MOLECULAR WEIGHT :
134.19
WISWESSER LINE NOTATION :
1U2OR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
63 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01855 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - E0737 No. of Facilities: 20 (estimated) No. of Industries: 1 No. of Occupations: 3 No. of Employees: 1929 (estimated) No. of Female Employees: 81 (estimated)

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ RTECS ]:
DA8575000

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • ALLYL CHLORIDE
  • Phenol
  • Allyl alcohol
  • allyl bromide
  • phenyl glycidyl ether
  • Allyl acetate
  • Allyl methyl carbonate
  • phenyl 2-propynyl ether
  • phenoxymethylthiirane
  • ALLYL PHENYL CARBONATE

DownStream

  • 1-allyl-2-methoxybenzene
  • Ethyl allylmalonate
  • Diethyl diallylmalonate
  • 3-Phenoxy-1,2-propanediol
  • (2-Methoxyphenyl)acetaldehyde
  • 4-(Phenoxymethyl)benzoic acid
  • allylcyclopentane
  • 1-Allylpiperidine
  • Allylbenzene
  • Biphenyl

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

SmI2/water/amine mediates cleavage of allyl ether protected alcohols: application in carbohydrate synthesis and mechanistic considerations.

Org. Lett. 5(22) , 4085-8, (2003)

[reaction: see text]. SmI2/H2O/amine provides selective cleavage of unsubstituted allyl ethers in good to excellent yields. This method is therefore useful in deprotection of alcohols and carbohydrate...

Pd-catalyzed synthesis of allylic silanes from allylic ethers.

Org. Lett. 12(1) , 28-31, (2010)

Allylic phenyl ethers serve as electrophiles toward Pd(0) en route to a variety of allylic silanes. The reactions can be run at room temperature in water as the only medium using micellar catalysis.

Stereoselective epoxidation of phenyl allyl ether by alkene-utilizing bacteria.

Appl. Microbiol. Biotechnol. 37(1) , 28-31, (1992)

Eighteen newly isolated ethene- and propene-utilizing bacteria were screened for the ability to produce phenyl glycidyl ether, a common precursor for the synthesis of beta blockers, from phenyl allyl ...


More Articles

Related Compounds

  • 1,3,5-Tris(allyloxy)benzene
  • 1-allyl-4-(allyloxy)benzene
  • 1-methoxy-4-(allyloxy)benzene
  • 2,4-dimethyl(allyloxy)benzene
  • ar-(allyloxy)benzenetrimethanol
  • 1-isocyanato-4-(allyloxy)benzene
  • Chloromethyl 3-{[(tert-butoxy)carbonyl]amino}bicyclo[3.1.0]hexane-1-carboxylate
  • Sodium 2-fluoro-3-methoxybenzene-1-sulfinate
  • Sodium 5-(ethoxycarbonyl)-2-fluoro-4-methylbenzene-1-sulfinate
  • Sodium 2-bromo-4-methanesulfonylbenzene-1-sulfinate
  • Sodium (3-chlorophenyl)methanesulfinate
  • rac-(5R,6S)-5-(aminomethyl)-1-cyclopropyl-6-(1-methyl-1H-pyrazol-4-yl)piperidin-2-one
  • 2-(Azidomethyl)-4-(3-nitrophenyl)oxolane
  • Sodium 3-methoxy-5-(methoxycarbonyl)thiophene-2-sulfinate
  • Sodium 8-oxo-5,6,7,8-tetrahydronaphthalene-2-sulfinate
  • Sodium 3-bromo-2-cyanobenzene-1-sulfinate
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