Aluminium 2-methyl-2-propanolate lithium (1:3:1)

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Names

[ CAS No. ]:
17476-04-9

[ Name ]:
Aluminium 2-methyl-2-propanolate lithium (1:3:1)

[Synonym ]:
EINECS 241-490-8
LithiuM Tri-tert-butoxyaluMinuM Hydride
Lithium tri-tert-but
Lithium tri-tert-butoxyaluminohydride
2-Propanol, 2-methyl-, aluminum lithium salt (3:1:1)
MFCD00011532
Lithium Tri-t-Butoxyaluminohydride
lithiumtri-tert-butoxyhydroaluminate
Aluminium 2-methyl-2-propanolate lithium (1:3:1)
Lithium tri-t-butoxyaluminium Hydride
Lithium tri-tert-butoxyaluminum
LTTBA
Aluminiumlithiumtri-tert-butoxidhydrid

Chemical & Physical Properties

[ Density]:
0.942 g/mL at 25 °C

[ Boiling Point ]:
84.6ºC at 760 mmHg

[ Melting Point ]:
300-319 °C (dec.)(lit.)

[ Molecular Formula ]:
C12H27AlLiO3

[ Molecular Weight ]:
253.264

[ Flash Point ]:
95 °F

[ Exact Mass ]:
253.193558

[ PSA ]:
27.69000

[ LogP ]:
3.79740

[ Vapour Pressure ]:
46mmHg at 25°C

[ Storage condition ]:
2-8°C

[ Stability ]:
Stable. Incompatible with alcohols. Reacts violently with water. Highly flammable.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
OJ5585000
CHEMICAL NAME :
Lithium aluminumtri-tert-butoxyhydride
CAS REGISTRY NUMBER :
17476-04-9
LAST UPDATED :
199712
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C12-H28-Al-O3.Li

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
32 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00620 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997

Safety Information

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R14/15;R19;R35

[ Safety Phrases ]:
S53-S26-S36/37/39-S43-S45-S16-S43B-S6A

[ RIDADR ]:
UN 3399 4.3/PG 1

[ WGK Germany ]:
1

[ RTECS ]:
OJ5585000

[ Packaging Group ]:
II

[ Hazard Class ]:
4.3

Related Compounds

  • Lithium 2-methyl-2-propanolate
  • ALUMINUM TERT-BUTANOLATE
  • Magnesium bis(2-methyl-2-propanolate)
  • Bis(1-dimethylamino-2-methyl-2-propanolate)lead (II), 98% (Pb(dmamp)2)
  • BARIUMTERT-BUTOXIDE
  • zirconium tert-butoxide
  • (2S)-2-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)propanoic acid
  • 3-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)-2-methylpropanoic acid
  • 2-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)-2-methylpropanoic acid
  • 5-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)hexanoic acid
  • (2RS,3SR)-3-[(3RS&,5RS&)-5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolane-3-amido]oxolane-2-carboxylic acid
  • 3-[2-({5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolan-3-yl}formamido)ethoxy]propanoic acid
  • rac-1-[(3R,5R)-5-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]oxolane-3-carbonyl]-3-methylpyrrolidine-3-carboxylic acid
  • 2-(1-{3-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclohexanecarbonyl}azetidin-3-yl)acetic acid
  • Perfluoro-1-[13C8]octanesulfonamide
  • rac-2-{1-[(1R,2S)-2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]cyclopropyl]-N-[2-(methylsulfanyl)ethyl]formamido}acetic acid
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