(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

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Names

[ CAS No. ]:
174810-09-4

[ Name ]:
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

[Synonym ]:
MFCD02684551
(R,R)-DACH-naphthyl trost ligand
2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

Chemical & Physical Properties

[ Melting Point ]:
224-231ºC

[ Molecular Formula ]:
C52H44N2O2P2

[ Molecular Weight ]:
790.86500

[ Exact Mass ]:
790.28800

[ PSA ]:
85.38000

[ LogP ]:
9.76220

MSDS

Safety Information

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Precursor & DownStream

Precursor

  • (1R,2R)-(-)-1,2-Diaminocyclohexane
  • 2-DIPHENYLPHOSPHINO-1-NAPHTHOIC ACID
  • Methyl 2-hydroxy-1-naphthoate
  • Methyl 2-diphenylphosphino-1-n
  • METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE

DownStream

Articles

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

Chem. Rev. 96 , 395, (1996)

Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

Chem. Rev. 103 , 2921, (2003)

Trost, B.M. et al.

J. Am. Chem. Soc. 124 , 11616, (2004)


More Articles


Related Compounds

  • 2-Amino-5-bromo-6-oxo-1,6-dihydropyridine-3-carbonitrile
  • 3-(4-Bromomethyl-phenyl)-isoxazole-5-carboxylic acid amide
  • Benzyl 3-amino-3-(carbamoylmethyl)pyrrolidine-1-carboxylate
  • 1-(2-Chloro-6-methylpyridin-3-yl)cyclobutanol
  • Benzyl 4-amino-4-(carbamoylmethyl)piperidine-1-carboxylate
  • {(3aR,4R,6R,6aR)-6-[6-(dibenzoylamino)-9H-purin-9-yl]-2,2-dioxidotetrahydrofuro[3,4-d][1,3,2]dioxathiol-4-yl}methyl benzoate
  • Des-[N-(4-chloro-2-methyl-6[((methylamino)carboyl))phenyl]] Chlorantraniliprole
  • (2S)-1,1,1-trifluoro-3-(naphthalen-1-yl)propan-2-amine
  • (2S)-1,1,1-trifluoro-3-(naphthalen-2-yl)propan-2-amine
  • N-[2-amino-4-(4-methylphenyl)-1,3-thiazol-5-yl]acetamide
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