(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

Suppliers

Names

[ Name ]:
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

[Synonym ]:
MFCD02684551
(R,R)-DACH-naphthyl trost ligand
2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

Chemical & Physical Properties

[ Melting Point ]:
224-231ºC

[ Molecular Formula ]:
C₅₂H₄₄N₂O₂P₂

[ Molecular Weight ]:
790.86500

[ Exact Mass ]:
790.28800

[ PSA ]:
85.38000

[ LogP ]:
9.76220

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Precursor & DownStream

Precursor

(1R,2R)-(-)-1,2-Diaminocyclohexane
2-DIPHENYLPHOSPHINO-1-NAPHTHOIC ACID
Methyl 2-hydroxy-1-naphthoate
Methyl 2-diphenylphosphino-1-n
METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE

DownStream

Articles

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

Chem. Rev. 96 , 395, (1996)

Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

Chem. Rev. 103 , 2921, (2003)

Trost, B.M. et al.

J. Am. Chem. Soc. 124 , 11616, (2004)

4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
2-methyl-1-(1-methyl-1H-1,2,3-triazol-5-yl)propan-2-amine
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
tert-Butyl-DL-alanine
N-[1-(2-Methoxypyridin-4-yl)cyclopropyl]prop-2-enamide