(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

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Names

[ CAS No. ]:
174810-09-4

[ Name ]:
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

[Synonym ]:
MFCD02684551
(R,R)-DACH-naphthyl trost ligand
2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

Chemical & Physical Properties

[ Melting Point ]:
224-231ºC

[ Molecular Formula ]:
C52H44N2O2P2

[ Molecular Weight ]:
790.86500

[ Exact Mass ]:
790.28800

[ PSA ]:
85.38000

[ LogP ]:
9.76220

MSDS

Safety Information

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Precursor & DownStream

Precursor

  • (1R,2R)-(-)-1,2-Diaminocyclohexane
  • 2-DIPHENYLPHOSPHINO-1-NAPHTHOIC ACID
  • Methyl 2-hydroxy-1-naphthoate
  • Methyl 2-diphenylphosphino-1-n
  • METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE

DownStream

Articles

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

Chem. Rev. 96 , 395, (1996)

Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

Chem. Rev. 103 , 2921, (2003)

Trost, B.M. et al.

J. Am. Chem. Soc. 124 , 11616, (2004)


More Articles


Related Compounds

  • (1R,2R)-(+)-1,2-Diphenylethylenediamine
  • (R,R)-(+)-1,2-DI(1-NAPHTHYL)-1,2-ETHANEDIOL
  • (1R,2R)-Trost ligand
  • (1R,2R)-(+)-1,2-Diaminocyclohexane L-Tartrate
  • trans-2-Morpholin-4-ylcyclohexanol
  • (1R,2R)-1,2-Diphenylethylenediamine
  • meso-1,2-Diphenylethylenediamine
  • (1-Phenylbutyl)hydrazine
  • 4-(3-Bromo-phenyl)-4-methoxy-tetrahydro-pyran
  • (E)-Methyl 2-(2-methoxyvinyl)benzoate
  • 3-{4-[2-(2,2,2-Trifluoroethoxy)phenyl]piperazin-1-yl}propylamine
  • (2,6-Difluoro-3-nitrophenyl)trimethylstannane
  • (S)-1-(2-Amino-2-carboxyethyl)-1H-imidazole-4-carboxylic acid
  • 5,5-Dimethyl-7alpha-amino-6,7-dihydro-5H-thieno[3,2-b]pyran-6beta-ol
  • 4-((tetrahydro-2H-pyran-2-yloxy)methyl)piperidine
  • Sodium aconitate, (E)-
  • 2,4-Dimethoxy-6-(5-methoxy-3-methylpyrazol-1-yl)pyrimidine
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