(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

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Names

[ Name ]:
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis-(2-diphenylphosphino-1-naphthoyl)

[Synonym ]:
MFCD02684551
(R,R)-DACH-naphthyl trost ligand
2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

Chemical & Physical Properties

[ Melting Point ]:
224-231ºC

[ Molecular Formula ]:
C₅₂H₄₄N₂O₂P₂

[ Molecular Weight ]:
790.86500

[ Exact Mass ]:
790.28800

[ PSA ]:
85.38000

[ LogP ]:
9.76220

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
NONH for all modes of transport

Precursor & DownStream

Precursor

(1R,2R)-(-)-1,2-Diaminocyclohexane
2-DIPHENYLPHOSPHINO-1-NAPHTHOIC ACID
Methyl 2-hydroxy-1-naphthoate
Methyl 2-diphenylphosphino-1-n
METHYL 2-TRIFLUOROMETHANESULFONYLOXY-1-NAPHTHOATE

DownStream

Articles

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

Chem. Rev. 96 , 395, (1996)

Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

Chem. Rev. 103 , 2921, (2003)

Trost, B.M. et al.

J. Am. Chem. Soc. 124 , 11616, (2004)

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