4-[4-(1-Hydroxyethyl)-2-methoxy-5-nitrophenoxy]butanoic Acid

Names

[ CAS No. ]:
175281-76-2

[ Name ]:
4-[4-(1-Hydroxyethyl)-2-methoxy-5-nitrophenoxy]butanoic Acid

[Synonym ]:
Hydroxyethyl photolinker

Chemical & Physical Properties

[ Density]:
1.333g/cm3

[ Boiling Point ]:
540.1ºC at 760 mmHg

[ Melting Point ]:
163-166ºC

[ Molecular Formula ]:
C₁₃H₁₇NO₇

[ Molecular Weight ]:
299.27700

[ Flash Point ]:
280.4ºC

[ Exact Mass ]:
299.10100

[ PSA ]:
121.81000

[ LogP ]:
2.42350

[ Vapour Pressure ]:
1.7E-12mmHg at 25°C

[ Index of Refraction ]:
1.561

MSDS

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

methyl 4-[4-(1-hydroxyethyl)-2-methoxy-5-nitrophenoxy]butyrate
ethyl 4-(4-(1-hydroxyethyl) -2-methoxy-5-nitrophenoxy)butanoate
Acetovanillone
4-(4-Acetyl-2-methoxyphenoxy)-butanoic Acid Ethyl Ester
methyl 4-(4-acetyl-2-methoxyphenoxy)butanoate
methyl 4-(4-acetyl-2-methoxy-5-nitrophenoxy)butyrate
4-(4-acetyl-2-methoxy-5-nitrophenoxy)butanoic acid
4-(4-Acetyl-2-methoxy-5-nitrophenoxy)-butanoic Acid Ethyl Ester

DownStream

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Model Studies for New o-Nitrobenzyl Photolabile Linkers: Substituent Effects on the Rates of Photochemical Cleavage.

J. Org. Chem. 62 , 2370, (1997)

Both a model phenacyl and o-nitrobenzyl photolabile linker from the literature along with four new o-nitrobenzyl linkers were prepared and the kinetics of their photolytic cleavage examined in solutio...

D.L. Whitehouse et a

Tetrahedron Lett. 38 , 7851, (1997)

(1-cyclopropyl-3-methyl-1H-pyrazol-4-yl)methanamine
{7,7-Dioxo-2-oxa-7lambda6-thiaspiro[4.4]nonan-1-yl}methanesulfonyl fluoride
6,6,6-Trifluorohexane-3-thiol
rac-(3R,4S)-4-cycloheptylpyrrolidin-3-ol
{7,7-Dimethyl-2-oxaspiro[4.5]decan-1-yl}methanesulfonyl fluoride
{8-Methyl-8-azaspiro[bicyclo[3.2.1]octane-3,3'-oxolane]-2'-yl}methanesulfonyl fluoride
{7,9-Dimethyl-2-oxaspiro[4.5]decan-1-yl}methanesulfonyl fluoride
2-(1,4-dimethyl-1H-pyrazol-3-yl)ethane-1-thiol
[8-(2-Methylpropyl)-2-oxa-8-azaspiro[4.5]decan-1-yl]methanesulfonyl fluoride
{2,6-Dioxaspiro[3.4]octan-5-yl}methanesulfonyl fluoride

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