4-[4-(1-Hydroxyethyl)-2-methoxy-5-nitrophenoxy]butanoic Acid

Names

[ CAS No. ]:
175281-76-2

[ Name ]:
4-[4-(1-Hydroxyethyl)-2-methoxy-5-nitrophenoxy]butanoic Acid

[Synonym ]:
Hydroxyethyl photolinker

Chemical & Physical Properties

[ Density]:
1.333g/cm3

[ Boiling Point ]:
540.1ºC at 760 mmHg

[ Melting Point ]:
163-166ºC

[ Molecular Formula ]:
C₁₃H₁₇NO₇

[ Molecular Weight ]:
299.27700

[ Flash Point ]:
280.4ºC

[ Exact Mass ]:
299.10100

[ PSA ]:
121.81000

[ LogP ]:
2.42350

[ Vapour Pressure ]:
1.7E-12mmHg at 25°C

[ Index of Refraction ]:
1.561

MSDS

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2918990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

methyl 4-[4-(1-hydroxyethyl)-2-methoxy-5-nitrophenoxy]butyrate
ethyl 4-(4-(1-hydroxyethyl) -2-methoxy-5-nitrophenoxy)butanoate
Acetovanillone
4-(4-Acetyl-2-methoxyphenoxy)-butanoic Acid Ethyl Ester
methyl 4-(4-acetyl-2-methoxyphenoxy)butanoate
methyl 4-(4-acetyl-2-methoxy-5-nitrophenoxy)butyrate
4-(4-acetyl-2-methoxy-5-nitrophenoxy)butanoic acid
4-(4-Acetyl-2-methoxy-5-nitrophenoxy)-butanoic Acid Ethyl Ester

DownStream

Customs

[ HS Code ]: 2918990090

[ Summary ]:
2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Model Studies for New o-Nitrobenzyl Photolabile Linkers: Substituent Effects on the Rates of Photochemical Cleavage.

J. Org. Chem. 62 , 2370, (1997)

Both a model phenacyl and o-nitrobenzyl photolabile linker from the literature along with four new o-nitrobenzyl linkers were prepared and the kinetics of their photolytic cleavage examined in solutio...

D.L. Whitehouse et a

Tetrahedron Lett. 38 , 7851, (1997)

2-[2-(Dimethylamino)-1,3-thiazol-5-yl]-2-methylpropanal
4-(Ethylsulfanyl)-3-methylbutan-1-amine
1-(3,5-Dichlorophenyl)-2-fluoroethan-1-ol
{1-[(2-Ethoxyphenyl)methyl]cyclopropyl}methanol
2-(2-Methanesulfonylphenyl)propanenitrile
(2S)-3-(3,4-dihydroxyphenyl)-2-({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)-2-methylpropanoic acid
tert-butyl N-(6-ethyl-2-methylpiperidin-3-yl)carbamate
4-[(4-acetylpiperazin-1-yl)methyl]-1-methyl-1H-pyrazole-3-carboxylic acid
Tert-butyl 2-[2-(ethylamino)ethyl]-1,1-dioxo-1lambda6-thiomorpholine-4-carboxylate
tert-butyl 5-(pyrrolidin-2-yl)-1H-1,2,3-triazole-4-carboxylate

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