5-Bromosalicylaldehyde

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Names

[ CAS No. ]:
1761-61-1

[ Name ]:
5-Bromosalicylaldehyde

[Synonym ]:
EINECS 217-167-2
MFCD00003330
5-Bromo-2-hydroxybenzaldehyde
5-Bromosalicylaldehyde
Benzaldehyde, 5-bromo-2-hydroxy-

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
247.3±20.0 °C at 760 mmHg

[ Melting Point ]:
102-106 °C(lit.)

[ Molecular Formula ]:
C7H5BrO2

[ Molecular Weight ]:
201.017

[ Flash Point ]:
103.4±21.8 °C

[ Exact Mass ]:
199.947281

[ PSA ]:
37.30000

[ LogP ]:
2.72

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.657

[ Storage condition ]:
Room temperature.

[ Water Solubility ]:
insoluble

MSDS

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2942000000

Synthetic Route

Precursor & DownStream

Precursor

  • 2-Methylbenzyl Alcohol
  • Salicylaldehyde
  • Formaldehyde
  • 4-Bromophenol
  • 6-bromo-2,2-dimethylbenzo[1,3]dioxin-4-one
  • p-Toluidine
  • Benzaldehyde,5-bromo-2-hydroxy-, oxime
  • Chloroform

DownStream

  • 5-(3-fluoro-4-methoxyphenyl)-2-hydroxybenzaldehyde
  • 5-(3,5-dimethylphenyl)-2-hydroxybenzaldehyde
  • 5-(3,4-dimethoxyphenyl)-2-hydroxybenzaldehyde
  • 3-(1,3-benzothiazol-2-yl)-6-bromochromen-2-imine
  • 6-bromo-3-(2-bromoacetyl)chromen-2-one
  • 5-(3,5-dimethoxyphenyl)-2-hydroxybenzaldehyde
  • 4-bromo-6-[(2-pyridin-2-ylethylamino)methylidene]cyclohexa-2,4-dien-1-one
  • 5-Bromo-2-hydroxybenzonitrile
  • 5-Bromo-2-[(4-chlorobenzyl)oxy]benzaldehyde
  • (5-AMINOBENZO[D]ISOXAZOL-3-YL)CARBAMICACIDTERT-BUTYLESTER

Customs

[ HS Code ]: 2913000090

[ Summary ]:
HS: 2913000090 halogenated, sulphonated, nitrated or nitrosated derivatives of products of heading 2912 Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:none Most favored nation tariff:5.5% General tariff:30.0%

Articles

Synthesis, structure, spectral characterization, electrochemistry and evaluation of antibacterial potentiality of a novel oxime-based palladium(II) compound.

Eur. J. Med. Chem. 89 , 59-66, (2014)

The title monomeric Pd(II) compound, [Pd(L)(Cl)], was synthesized in moderate yield out of the reaction of equimolar proportion of Na2[PdCl4] and 3-[(5-bromo-2-hydroxy-benzylidene)-hydrazono]-butan-2-...

Synthesis and characterization of 1,2-bis(2-(5-bromo-2-hydroxybenzilidenamino)-4-chlorophenoxy)ethane and its metal complexes: an experimental, theoretical, electrochemical, antioxidant and antibacterial study.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 118 , 632-42, (2014)

A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2-aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal sal...

Redox-active tetrahydrosalen (salan) complexes of titanium.

Dalton Trans. 40(43) , 11458-68, (2011)

A diarylamino-substituted N-methyl tetrahydrosalen (salan) ligand, (An2N)LH(2), is prepared in four steps and overall 53% yield from 5-bromosalicylaldehyde, with the key step a palladium-catalysed Har...


More Articles


Related Compounds

  • 5-bromosalicylaldehyde
  • 5-bromosalicylaldehyde azine
  • 5-bromosalicylaldehyde oxime
  • 3-nitro-5-bromosalicylaldehyde
  • 3-chloro-5-bromosalicylaldehyde
  • 3-methoxy-5-bromosalicylaldehyde
  • 3-Chloro-4-(morpholin-4-yl)aniline dihydrochloride
  • 1-{6-Methylthieno[2,3-d]pyrimidin-4-yl}piperidin-4-amine dihydrochloride
  • Ethyl 3-phenoxyazetidine-3-carboxylate
  • (2S,3R)-2-{[(benzyloxy)carbonyl](cyclopropyl)amino}-3-hydroxybutanoic acid
  • {2-Oxo-6-oxaspiro[3.4]octan-7-yl}methanesulfonamide
  • 6-Methoxy-2-(trifluoromethyl)pyridine-3-sulfonamide
  • 2-(4-Methyl-3-nitrophenyl)prop-2-en-1-amine hydrochloride
  • 4-Chloro-6-(perfluoroethyl)pyrimidin-2-amine
  • N-(4-amino-4-methylcyclohexyl)propane-2-sulfonamide hydrochloride
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 1-(1-phenylpropan-2-yl)-1H-pyrrole-2-carboxylate
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