4-Fluorobenzeneboronic acid

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Names

[ CAS No. ]:
1765-93-1

[ Name ]:
4-Fluorobenzeneboronic acid

[Synonym ]:
p-fluorophenylboronic acid
QBQR DF
4-Fluorophenylboronic Acid
p-fluorobenzeneboronic acid
(4-fluorophenyl)dihydroxyborane
(4-Fluorophenyl)boronic acid
Boronic acid, B-(4-fluorophenyl)-
MFCD00039136
4-Fluorobenzeneboronic acid
B-(4-Fluorophenyl)boronic acid

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
258.4±42.0 °C at 760 mmHg

[ Melting Point ]:
262-265 °C(lit.)

[ Molecular Formula ]:
C6H6BFO2

[ Molecular Weight ]:
139.92

[ Flash Point ]:
110.1±27.9 °C

[ Exact Mass ]:
140.044495

[ PSA ]:
40.46000

[ LogP ]:
1.64

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.509

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P280-P301 + P312 + P330-P305 + P351 + P338-P337 + P313

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-Bromo-4-fluorobenzene
  • 4-Fluorophenyltriflate
  • 4-Fluoroiodobenzene
  • 1-Chloro-4-fluorobenzene
  • 2-(4-FLUOROPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
  • Triisopropylborate
  • 4-Fluorophenylmagnesium bromide
  • Tetrahydroxydiboron
  • BUTYL BORATE
  • Tris(4-fluorophenyl)boroxin

DownStream

  • 4'-FluoroBiphenyl-4-carBoxylicacidethylester
  • 3-BROMO-4'-FLUOROBIPHENYL
  • 2-(4-fluorophenyl)-3-methylpyridine
  • 4'-Fluoro-3-biphenylol
  • 4-Fluorophenyl methyl sulfone
  • 1-Bromo-4-fluorobenzene
  • 4'-Fluoro-4-biphenylol
  • 4-(4-fluorophenyl)-4-hydroxy-1-cyclohexanone
  • 4-FLUORO-4'-METHYL-1,1'-BIPHENYL
  • 2-(4-Fluorophenyl)-1-phenylethanone

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Cationic palladium(II)-catalyzed addition of arylboronic acids to nitriles. One-step synthesis of benzofurans from phenoxyacetonitriles.

Org. Lett. 8 , 5987, (2006)

[Structure: see text] A cationic palladium complex catalyzed addition of arylboronic acids to nitriles to yield aryl ketones with moderate to good yields was developed. A one-step synthesis of benzofu...

Ruthenium(0)-catalyzed sp3 C-H bond arylation of benzylic amines using arylboronates.

Org. Lett. 7th ed., 14 , 1930-1933, (2012)

A Ru-catalyzed direct arylation of benzylic sp(3) carbons of acyclic amines with arylboronates is reported. This highly regioselective and efficient transformation can be performed with various combin...

Tandem-type Pd(II)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: a novel route to 4-aryl-2-quinolinones.

Chem. Commun. (Camb.) 36th ed., 48 , 4332-4334, (2012)

A novel catalytic method for synthesizing 4-aryl-2-quinolinones is reported. The process involves two mechanistically independent, sequential Pd(II)-catalyzed reactions--the oxidative Heck reaction an...


More Articles

Related Compounds

  • 3-Amino-4-fluorobenzeneboronic acid
  • 3-Cyano-4-fluorobenzeneboronic acid
  • 2-Chloro-4-fluorobenzeneboronic Acid
  • 3-Chloro-4-Fluorobenzeneboronic Acid
  • 2-methoxy-4-fluorobenzeneboronic acid
  • 3-Carboxy-4-fluorobenzeneboronic acid
  • 4-[(Phenylsulfonyl)methyl]aniline
  • 2-(3-(phenylsulfonyl)-1H-indol-1-yl)-N-(pyridin-3-yl)acetamide
  • N-(isoxazol-3-yl)-2-(3-(phenylsulfonyl)-1H-indol-1-yl)acetamide
  • N-(5-methylisoxazol-3-yl)-2-(3-(phenylsulfonyl)-1H-indol-1-yl)acetamide
  • 4-(2-(3-(phenylsulfonyl)-1H-indol-1-yl)acetamido)benzamide
  • 1-(4-methylpiperazin-1-yl)-2-(3-tosyl-1H-indol-1-yl)ethanone
  • 1-(4-ethylpiperazin-1-yl)-2-(3-tosyl-1H-indol-1-yl)ethanone
  • 6-Chloro-5,7-dimethyl-3,6-dihydro-2H-1,4-diazepine
  • 1-(4-acetylpiperazin-1-yl)-2-(3-tosyl-1H-indol-1-yl)ethanone
  • 2,6-Dimethoxy-alpha-methyl-benzeneethanamine,monohydrochloride
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