2-Chlorothiosanisole

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Names

[ CAS No. ]:
17733-22-1

[ Name ]:
2-Chlorothiosanisole

[Synonym ]:
2-Cl-phenyl methyl sulfide
2-CHLOROTHIOANISOLE
1-chloranyl-2-methylsulfanyl-benzene
ortho-chlorophenyl methyl sulfide
2-Chloro Thioanisole
2-Chlorothiosanisole
2-Chlorophenyl methyl sulphide
o-ClC6H4SMe
1-Chloro-2-(methylsulfanyl)benzene
Benzene, 1-chloro-2-(methylthio)-
2-Chlorophenyl methyl sulfide
1-Chloro-2-(methylthio)benzene
MFCD00040124

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
211.1±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H7ClS

[ Molecular Weight ]:
158.648

[ Flash Point ]:
69.4±0.0 °C

[ Exact Mass ]:
157.995697

[ PSA ]:
25.30000

[ LogP ]:
3.46

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.588

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 3334

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

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Precursor & DownStream

Precursor

  • 2-Chlorothiophenol
  • methyl iodide
  • 1,2-Dichlorobenzene
  • Sodium thiomethoxide
  • Methyl mercaptan
  • SODIUM 2-CHLOROBENZENESULFINATE
  • 2-chlorobenzenediazonium hydrogensulfate

DownStream

  • (2-Chloro-4-(chloromethyl)phenyl)(methyl)sulfane
  • [3-Chloro-4-(methylsulfanyl)phenyl]acetic acid
  • 2-(Methylsulfonyl)benzenesulfonyl chloride
  • 1,2-bis-methanesulfonyl-benzene
  • 2-(methylthio)benzonitrile
  • 1-(3-CHLORO-4-(METHYLTHIO)PHENYL)ETHANONE
  • 1-chloro-2-[(S)-methylsulfinyl]benzene
  • 1-CHLORO-2-(METHYLSULFINYL)BENZENE
  • 2-chlorophenyl methyl sulfone

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Analysis of chlorophenylmethylsulfides in the urine of rats injected with chlorobenzene by high performance liquid chromatography.

Ind. Health 23(4) , 283-7, (1985)

The proximate coupling constant, 5 J (H, CH3), and the torsional mobility of the thiomethyl group in some thioanisole derivatives. Schaefer T, et al.

Can. J. Chem. 69(4) , 620-624, (1991)

The preferred conformations of 2, 4-dichlorophenol, 2, 4-dichloroanisole and their sulphur analogues. Lumbroso H, et al.

J. Mol. Struct. 43(1) , 87-95, (1978)


More Articles

Related Compounds

  • 2-Chlorothiosanisole
  • 2-(4-Methylpiperazin-1-yl)-5-(trifluoromethyl)aniline
  • 2-[(4-aminobenzoyl)-benzylamino]ethyl-diethylazanium,chloride
  • 2-methyl-2-methylsulfanylpropanenitrile
  • 2-((4-(1-METHYL-4-(PYRIDIN-4-YL)-1H-PYRAZOL-3-YL)PHENOXY)METHYL)QUINOLINE SUCCINATE
  • 2-(3-Chloropropoxy)-1-methoxy-4-nitrobenzene