BIS((3AR,8AS)-8,8A-DIHYDRO-3AH-INDENO[1,2-D]OXAZOL-2-YL)METHANE

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Names

[ CAS No. ]:
180186-94-1

[ Name ]:
BIS((3AR,8AS)-8,8A-DIHYDRO-3AH-INDENO[1,2-D]OXAZOL-2-YL)METHANE

[Synonym ]:
MFCD00674092
8H-Indeno[1,2-d]oxazole, 2,2'-methylenebis[3a,8a-dihydro-, (3aR,8aS,3'aR,8'aS)-
[3aR-[2(3'aR*,8'aS*),3'aβ,8'aβ]]-(+)-2,2'-Methylenebis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole]
[3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-Methylenebis[3a,8a
1-methylsulfinyl-1-methylthio-3-benzyloxycyclobutane
Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)methane
(3aR,8aS,3a'R,8a'S)-2,2'-Methylenebis(8,8a-dihydro-3aH-indeno[1,2-d][1,3]oxazole)

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
493.2±45.0 °C at 760 mmHg

[ Melting Point ]:
225ºC

[ Molecular Formula ]:
C21H18N2O2

[ Molecular Weight ]:
330.380

[ Flash Point ]:
201.9±21.2 °C

[ Exact Mass ]:
330.136841

[ PSA ]:
43.18000

[ LogP ]:
2.35

[ Vapour Pressure ]:
0.0±1.2 mmHg at 25°C

[ Index of Refraction ]:
1.778

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

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Precursor & DownStream

Precursor

  • (1R,2S)-1-Amino-2,3-dihydro-1H-inden-2-ol
  • Diethyl propanediimidate dihydrochloride

DownStream

Articles

Gant, T.G. Meyers, A.I.

Tetrahedron 50 , 2297, (1994)

Pfaltz, A.

Acc. Chem. Res. 26 , 339, (1993)

Bolm, C.

Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)


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