(Trimethylsilyl)diazomethane

Suppliers

Names

[ CAS No. ]:
18107-18-1

[ Name ]:
(Trimethylsilyl)diazomethane

[Synonym ]:
TMSCHN2
(Trimethylsilyl)diazomethane,approx. 2M
(Trimethylsilyl)diazomethane,approx. 2.0M
Diazomethyltrimethyl Silane
MFCD00053946
Trimethylsil
trimethylsilyldiazomethane
(diazomethyl)trimethylsilane
diazomethyl-trimethyl-silane
Silane, (diazomethyl)trimethyl-
(Trimethylsilyl)diazomethane
(Diazomethyl)(trimethyl)silane
trimethylsilyl diazomethane
Diazo((trimethylsilyl))methane
TMS-Diazomethane
(Diazomethyl)trimethylsilane,2M in hexane

Chemical & Physical Properties

[ Density]:
0.773 g/mL at 25 °C

[ Boiling Point ]:
96 °C

[ Molecular Formula ]:
C4H10N2Si

[ Molecular Weight ]:
114.221

[ Flash Point ]:
−31 °F

[ Exact Mass ]:
114.061325

[ PSA ]:
37.39000

[ LogP ]:
0.17

[ Index of Refraction ]:
1.4362

[ Storage condition ]:
Refrigerator

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H330-H336-H350-H370

[ Supplemental HS ]:
May form explosive peroxides., Repeated exposure may cause skin dryness or cracking.

[ Precautionary Statements ]:
P201-P210-P280-P308 + P311-P370 + P378-P403 + P235

[ Target Organs ]:
Lungs

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Highlyflammable;Xn:Harmful;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R38;R48/20;R51/53;R62;R65

[ Safety Phrases ]:
S9-S16-S29-S33-S36/37-S61-S62

[ RIDADR ]:
UN 1208 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Ionic complex of risedronate with positively charged deoxycholic acid derivative: evaluation of physicochemical properties and enhancement of intestinal absorption in rats.

Arch. Pharm. Res. 37(12) , 1560-9, (2014)

Risedronate is widely used clinically to treat osteoporosis, Paget's disease, hypercalcemia, bone metastasis, and multiple myeloma. However, its oral efficacy is restricted due to its low bioavailabil...

Evaluation of four derivatization methods for the analysis of fatty acids from green leafy vegetables by gas chromatography.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 990 , 150-7, (2015)

Green leafy vegetables are valuable secondary sources of nutrients, including lipids, commonly consumed in developing countries. However, method development for the analysis of fatty acids is usually ...

Liquid chromatography-mass spectrometry analysis of five bisphosphonates in equine urine and plasma.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 998-999 , 1-7, (2015)

Bisphosphonates are used in the management of skeletal disorder in humans and horses, with tiludronic acid being the first licensed veterinary medicine in the treatment of lameness associated with deg...


More Articles


Related Compounds

  • (trimethylsilyl)diazomethane
  • phenyl(trimethylsilyl)diazomethane
  • diazomethyl(dimethyl)silane
  • Trimethylsilyl (2S)-2-[(trimethylsilyl)oxy]propanoate
  • trimethylsilyl 11-cyanoundecanoate
  • (Trimethylsilyl)methyl 3-morpholinecarboxylate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • N-((3-bromophenyl)(tosyl)methyl)formamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide