(Trimethylsilyl)diazomethane

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Names

[ CAS No. ]:
18107-18-1

[ Name ]:
(Trimethylsilyl)diazomethane

[Synonym ]:
TMSCHN2
(Trimethylsilyl)diazomethane,approx. 2M
(Trimethylsilyl)diazomethane,approx. 2.0M
Diazomethyltrimethyl Silane
MFCD00053946
Trimethylsil
trimethylsilyldiazomethane
(diazomethyl)trimethylsilane
diazomethyl-trimethyl-silane
Silane, (diazomethyl)trimethyl-
(Trimethylsilyl)diazomethane
(Diazomethyl)(trimethyl)silane
trimethylsilyl diazomethane
Diazo((trimethylsilyl))methane
TMS-Diazomethane
(Diazomethyl)trimethylsilane,2M in hexane

Chemical & Physical Properties

[ Density]:
0.773 g/mL at 25 °C

[ Boiling Point ]:
96 °C

[ Molecular Formula ]:
C4H10N2Si

[ Molecular Weight ]:
114.221

[ Flash Point ]:
−31 °F

[ Exact Mass ]:
114.061325

[ PSA ]:
37.39000

[ LogP ]:
0.17

[ Index of Refraction ]:
1.4362

[ Storage condition ]:
Refrigerator

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H302-H330-H336-H350-H370

[ Supplemental HS ]:
May form explosive peroxides., Repeated exposure may cause skin dryness or cracking.

[ Precautionary Statements ]:
P201-P210-P280-P308 + P311-P370 + P378-P403 + P235

[ Target Organs ]:
Lungs

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Highlyflammable;Xn:Harmful;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R38;R48/20;R51/53;R62;R65

[ Safety Phrases ]:
S9-S16-S29-S33-S36/37-S61-S62

[ RIDADR ]:
UN 1208 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
2931900090

Synthetic Route

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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Related Compounds

  • (trimethylsilyl)diazomethane
  • phenyl(trimethylsilyl)diazomethane
  • diazomethyl(dimethyl)silane
  • Trimethylsilyl (2S)-2-[(trimethylsilyl)oxy]propanoate
  • trimethylsilyl 11-cyanoundecanoate
  • (Trimethylsilyl)methyl 3-morpholinecarboxylate