METHYL 8-CHLORO-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE-7-CARBOXYLATE

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Names

[ CAS No. ]:
181531-14-6

[ Name ]:
METHYL 8-CHLORO-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE-7-CARBOXYLATE

[Synonym ]:
(R)-Stericol(R)
(R)-Greene's alcohol
(R)-(+)-STERICOL
Methyl 8-chloro-6-(trifluoromethyl)imidazo[1,2-a]pyridine-7-carboxylate
1-(2,4,6-triisopropylphenyl)ethanol
(R)-1-(2,4,6-triisopropylphenyl)ethanol

Chemical & Physical Properties

[ Melting Point ]:
86-90ºC

[ Molecular Formula ]:
C10H6ClF3N2O2

[ Molecular Weight ]:
278.61500

[ Exact Mass ]:
278.00700

[ PSA ]:
43.60000

[ LogP ]:
2.79310

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • (R)-2-((1-(2,4,6-triisopropylphenyl)ethoxy)carbonyl)benzoic acid
  • 1,3,5-Triisopropylbenzene
  • (1S)-1-[2,4,6-tri(propan-2-yl)phenyl]ethanol
  • 2',4',6'-triisopropylacetophenone
  • 1'-(2'',4'',6''-triisopropylphenyl)ethyl acetoxyacetate
  • 1'-(2'',4'',6''-triisopropylphenyl)ethyl 2,2-dihydroxyacetate

DownStream

Articles

New asymmetric approach to natural pyrrolizidines: synthesis of (+)-amphorogynine A, (+)-amphorogynine D, and (+)-retronecine.

J. Org. Chem. 70 , 8352-8363, (2005)

Three natural pyrrolizidines, (+)-amphorogynines A and D and (+)-retronecine, have been prepared from a common lactam intermediate. This central compound, in turn, was synthesized in diastereomericall...

A New Asymmetric Carbon-Carbon Bond Forming Reaction: Four-Component Stereoselective Synthesis of (Z)-4,6-Dihydroxy-3-methylalk-2-enyl Methyl Sulfones This work was supported by the Swiss National Science Foundation.

Angew. Chem. Int. Ed. Engl. 39 , 1806, (2000)

Hamel, M., et al.

Tetrahedron Asymmetry 16 , 3406-3415, (2005)


More Articles

Related Compounds

  • 1-(3-amino-1H-pyrazol-5-yl)ethanol
  • Ethyl 3-((tert-butoxycarbonyl)amino)-2-(4-(((triisopropylsilyl)oxy)methyl)phenyl)propanoate
  • methyl 2-((R)-2-(tert-butoxycarbonylamino)propanamido)-3-hydroxypropanoate
  • 6-(methoxycarbonyl)-3,4-dihydro-2H-1-benzopyran-8-carboxylic acid
  • N-(3-Difluoromethoxy-phenyl)-4-methyl-3-[4-(2,2,2-trifluoro-acetyl)-piperazin-1-yl]-benzenesulfonamide
  • Methyl 2-[3-chloro-6-(methoxy)-1,5-naphthyridin-4-yl]-2-propenoate
  • 7-Chloro-3-oxo-3,4-dihydro-2H-pyrido[3,2-b][1,4]oxazine-6-carbaldehyde
  • 7-bromo-6-chloro-3,4-dihydro-2H-1-benzopyran-4-one
  • 1-(4-Methylphenyl)-2-(1-pyrrolidinyl)-1-butanone
  • Methyl 5-(4-aminobutyl)thiophene-2-carboxylate
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