METHYL 8-CHLORO-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE-7-CARBOXYLATE

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Names

[ CAS No. ]:
181531-14-6

[ Name ]:
METHYL 8-CHLORO-6-(TRIFLUOROMETHYL)IMIDAZO[1,2-A]PYRIDINE-7-CARBOXYLATE

[Synonym ]:
(R)-Stericol(R)
(R)-Greene's alcohol
(R)-(+)-STERICOL
Methyl 8-chloro-6-(trifluoromethyl)imidazo[1,2-a]pyridine-7-carboxylate
1-(2,4,6-triisopropylphenyl)ethanol
(R)-1-(2,4,6-triisopropylphenyl)ethanol

Chemical & Physical Properties

[ Melting Point ]:
86-90ºC

[ Molecular Formula ]:
C10H6ClF3N2O2

[ Molecular Weight ]:
278.61500

[ Exact Mass ]:
278.00700

[ PSA ]:
43.60000

[ LogP ]:
2.79310

MSDS

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Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

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Precursor & DownStream

Precursor

  • (R)-2-((1-(2,4,6-triisopropylphenyl)ethoxy)carbonyl)benzoic acid
  • 1,3,5-Triisopropylbenzene
  • (1S)-1-[2,4,6-tri(propan-2-yl)phenyl]ethanol
  • 2',4',6'-triisopropylacetophenone
  • 1'-(2'',4'',6''-triisopropylphenyl)ethyl acetoxyacetate
  • 1'-(2'',4'',6''-triisopropylphenyl)ethyl 2,2-dihydroxyacetate

DownStream

Articles

New asymmetric approach to natural pyrrolizidines: synthesis of (+)-amphorogynine A, (+)-amphorogynine D, and (+)-retronecine.

J. Org. Chem. 70 , 8352-8363, (2005)

Three natural pyrrolizidines, (+)-amphorogynines A and D and (+)-retronecine, have been prepared from a common lactam intermediate. This central compound, in turn, was synthesized in diastereomericall...

A New Asymmetric Carbon-Carbon Bond Forming Reaction: Four-Component Stereoselective Synthesis of (Z)-4,6-Dihydroxy-3-methylalk-2-enyl Methyl Sulfones This work was supported by the Swiss National Science Foundation.

Angew. Chem. Int. Ed. Engl. 39 , 1806, (2000)

Hamel, M., et al.

Tetrahedron Asymmetry 16 , 3406-3415, (2005)


More Articles

Related Compounds

  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 1-(3,5-Dichlorophenyl)cyclobutanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 1-{4-[(Difluoromethyl)sulfanyl]phenyl}ethan-1-amine hydrochloride
  • 3-(5-Propoxypiperidin-3-yl)propanoic acid